Chain-growth condensation polymerization for the synthesis of well-defined condensation polymers and π-conjugated polymers

T Yokozawa, A Yokoyama - Chemical reviews, 2009 - ACS Publications
Condensation polymerization is an important method of polymerization that yields not only
engineering plastics such as polyamides, polyesters, and polyimides but also π-conjugated …

Suzuki polycondensation: Polyarylenes à la carte

J Sakamoto, M Rehahn, G Wegner… - Macromolecular rapid …, 2009 - Wiley Online Library
This review draws a rather comprehensive picture of how Suzuki polycondensation was
discovered in 1989 and how it was subsequently developed into the most powerful …

50th Anniversary Perspective: Polymer Brushes: Novel Surfaces for Future Materials

WL Chen, R Cordero, H Tran, CK Ober - Macromolecules, 2017 - ACS Publications
Polymer brushes have become a significant focus of polymer research with the need for
straightforward and versatile surface modification. With the development of controlled radical …

The development of conjugated polymers as the cornerstone of organic electronics

RM Pankow, BC Thompson - Polymer, 2020 - Elsevier
The expansion of the field of organic electronics has hinged upon structural and
fundamental developments in the field of conjugated polymers. Conjugated polymers allow …

Poly (3-hexylthiophene): synthetic methodologies and properties in bulk heterojunction solar cells

A Marrocchi, D Lanari, A Facchetti… - Energy & Environmental …, 2012 - pubs.rsc.org
Poly (3-hexylthiophene)(P3HT) remains of significant importance as a prototypical
benchmark hole conductor material in Organic Photovoltaics (OPVs). In this review we …

Kumada Catalyst‐Transfer Polycondensation: Mechanism, Opportunities, and Challenges

A Kiriy, V Senkovskyy, M Sommer - Macromolecular rapid …, 2011 - Wiley Online Library
Kumada catalyst‐transfer polycondensation (KCTP) is a new but rapidly developing method
with great potential for the preparation of well‐defined conjugated polymers (CPs). The …

Conjugated polymer synthesis via catalyst-transfer polycondensation (CTP): mechanism, scope, and applications

ZJ Bryan, AJ McNeil - Macromolecules, 2013 - ACS Publications
The recent discovery of a living, controlled chain-growth method for synthesizing π-
conjugated polymers has ignited the field and led to the development of many new …

Random catalyst walking along polymerized poly (3-hexylthiophene) chains in Kumada catalyst-transfer polycondensation

R Tkachov, V Senkovskyy, H Komber… - Journal of the …, 2010 - ACS Publications
A “walking” process of Ni catalysts during Kumada catalyst-transfer polycondensation along
polymerizing poly (3-hexylthiophene), P3HT, chains was investigated. To simplify polymer …

Controlled polymerizations for the synthesis of semiconducting conjugated polymers

K Okamoto, CK Luscombe - Polymer Chemistry, 2011 - pubs.rsc.org
Conjugated polymers have been under active development since the 1970s as the active
material in organic field-effect transistors (OFETs), photovoltaic devices and the emissive …

Mechanistic Studies on Ni(dppe)Cl2-Catalyzed Chain-Growth Polymerizations: Evidence for Rate-Determining Reductive Elimination

EL Lanni, AJ McNeil - Journal of the American Chemical Society, 2009 - ACS Publications
The mechanisms for Ni (dppe) Cl2-catalyzed chain-growth polymerization of 4-bromo-2, 5-
bis (hexyloxy) phenylmagnesium chloride and 5-bromo-4-hexylthiophen-2-ylmagnesium …