Transition metal catalysis is of utmost importance for the development of sustainable
processes in academia and industry. The activity and selectivity of metal complexes are …

The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

Water oxidation is a key chemical transformation for the conversion of solar energy into
chemical fuels. Our review focuses on recent work on robust earth-abundant heterogeneous …

The oxygen reduction reaction (ORR) is a key component of biological processes and
energy technologies. This Review provides a comprehensive report of soluble molecular …

The chalcogen bond (ChB) is defined as a noncovalent interaction between the electron
density deficient region (so-called as σ or π hole) of a covalently bonded chalcogen atom …

The development of catalytic systems capable of oxygenating unactivated C–H bonds with
excellent site-selectivity and functional group tolerance under mild conditions remains a …

Transition metals can assemble to form multinuclear complexes by engaging in direct metal-
to-metal interactions. Metal–metal covalent bonds provide a large perturbation in electronic …

We report here on a new series of CO2-reducing molecular catalysts based on Earth-
abundant elements that are very selective for the production of formic acid in …

Selective functionalization of unactivated C–H bonds, water oxidation, and dioxygen
reduction are extremely important reactions in the context of finding energy carriers and …

At the core of many important energy conversion processes in chemistry and biology are
oxidation-reduction reactions in which both electrons and protons are transferred. An …