Glycosyl radical functionalization is one of the central topics in synthetic carbohydrate
chemistry. Recent advances in metal‐catalyzed cross‐coupling chemistry and …

Conspectus Efficient construction of ubiquitous carbon–carbon bonds between two
electrophiles has garnered interest in recent decades, particularly if it is mediated by …

Cross-electrophile coupling (XEC), defined by us as the cross-coupling of two different σ-
electrophiles that is driven by catalyst reduction, has seen rapid progression in recent years …

Carbohydrates play important roles in medicinal chemistry and biochemistry. However, their
synthesis relies on specially designed glycosyl donors, which are often unstable and require …

Stereochemically pure saccharides have indispensable roles in fields ranging from
medicinal chemistry to materials science and organic synthesis. However, the development …

We herein report a method that enables the generation of glycosyl radicals under highly
acidic conditions. Key to the success is the design and use of glycosyl sulfinates as radical …

Glycosyl donor activation emerged as an enabling technology for anomeric
functionalization, but aimed primarily at O-glycosylation. In contrast, we herein disclose …

Oligosaccharides are the ubiquitous molecules of life. In order to translate human
bioglycosylation into clinical applications, homogeneous samples of oligosaccharides and …

Comprehensive Summary C‐Glycosides are critical, naturally occurring products and
medicinal candidates, and extensive efforts have been made to explore efficient approaches …

The selective functionalization of carbohydrates holds a central position in synthetic
carbohydrate chemistry, driving the ongoing quest for ideal approaches to manipulate these …