The study of transition metal complexes linked with 1, 2, 3-triazoles has gained significant
attention due to their potential as effective catalysts in various chemical reactions. The 1, 2, 3 …

As one of the abundant and inexpensive metals on the earth, copper has demonstrated
broad applications in synthetic chemistry and catalysis. Among these copper-catalyzed …

gem-Hydrogenation of an internal alkyne with the aid of [Cp* RuCl] 4 as the precatalyst is a
highly unorthodox transformation, in which one C atom of the triple bond is transformed into …

The only recently discovered gem-hydrogenation of internal alkynes is a fundamentally new
transformation, in which both H atoms of dihydrogen are transferred to the same C atom of a …

The mechanism of Ru (II)-catalyzed gem-hydrogenation of 1, 3-enynes was studied with the
aid of DFT calculations. The origins of cyclization selectivity involved in the two Ru (II) …

Pt (II) alkylidene 1a has been reacted with terminal alkynes to afford ylide complexes 3a–d,
resulting from electrophilic activation of the CC bond and its insertion into the platinacyclic …

Transmetallation of zinc μ-methylene species to various metal chlorides has been attempted
to generate early transition metal methylene species. A dinuclear chromium μ-methylene …

The ruthenium-catalyzed [2+ 2] and homo Diels–Alder [2+ 2+ 2] cycloadditions of
norbornadiene with disubstituted alkynes are investigated using density functional theory …

During the coverage period of this chapter, reviews and highlights have appeared on the
following topics: Markovnikov selectivity of electrophilic additions of HF and HCl to non …

Engineered alkane dehydrohalogenases (HLDs) have been shown to effect
transhalogenation. Pre‐organization of geranyllinalool and its esters in a self‐assembled …