Structural and functional aspects of metal sites in biology

RH Holm, P Kennepohl, EI Solomon - Chemical reviews, 1996 - ACS Publications
The field of bioinorganic chemistry is at a propitious stage of development. Ever more
complex metallobiomolecules are isolated and purified, physical methodologies and …

Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates

M Costas, MP Mehn, MP Jensen, L Que - Chemical reviews, 2004 - ACS Publications
There have been significant advances in our understanding of mononuclear nonheme iron
oxygenases since our 1996 Chemical Reviews article, 1 promoted in large part by the many …

Geometric and electronic structure/function correlations in non-heme iron enzymes

EI Solomon, TC Brunold, MI Davis, JN Kemsley… - Chemical …, 2000 - ACS Publications
In recent years, significant progress has been made in understanding the geometric and
electronic structures of the active sites of non-heme iron enzymes and the contributions of …

The β-ketoadipate pathway and the biology of self-identity

CS Harwood, RE Parales - Annual review of microbiology, 1996 - annualreviews.org
The β-ketoadipate pathway is a chromosomally encoded convergent pathway for aromatic
compound degradation that is widely distributed in soil bacteria and fungi. One branch …

Genetic and biochemical investigations on bacterial catabolic pathways for lignin-derived aromatic compounds

E Masai, Y Katayama, M Fukuda - Bioscience, biotechnology, and …, 2007 - jstage.jst.go.jp
Lignins are the most abundant aromatic compounds in nature, and their decomposition is
essential to the terrestrial carbon cycle. White rot fungi secreting phenol oxidases are …

Dioxygen activation by enzymes with mononuclear non-heme iron active sites

L Que Jr, RYN Ho - Chemical reviews, 1996 - ACS Publications
Oxygen-activating enzymes with mononuclear nonheme iron active sites participate in many
metabolically important reactions that have environmental, pharmaceutical, and medical …

The ins and outs of ring-cleaving dioxygenases

FH Vaillancourt, JT Bolin, LD Eltis - Critical Reviews in …, 2006 - Taylor & Francis
Ring-cleaving dioxygenases catalyze the oxygenolytic fission of catecholic compounds, a
critical step in the aerobic degradation of aromatic compounds by bacteria. Two classes of …

Structural and mechanistic studies on 2-oxoglutarate-dependent oxygenases and related enzymes

CJ Schofield, Z Zhang - Current opinion in structural biology, 1999 - Elsevier
Mononuclear nonheme-Fe (II)-dependent oxygenases comprise an extended family of
oxidising enzymes, of which the 2-oxoglutarate-dependent oxygenases and related …

Dioxygenase enzymes: catalytic mechanisms and chemical models

TDH Bugg - Tetrahedron, 2003 - Elsevier
1. Introduction 7075 1.1. Di-oxygenase and mono-oxygenase enzymes 7075 1.2. Oxygen
activation by metal ions 7076 1.3. Reactivity of alkyl hydroperoxide intermediates 7077 2 …

Ethnicity influences the gut microbiota of individuals sharing a geographical location: a cross-sectional study from a middle-income country

J Dwiyanto, MH Hussain, D Reidpath, KS Ong… - Scientific reports, 2021 - nature.com
No studies have investigated the influence of ethnicity in a multi-ethnic middle-income
country with a long-standing history of co-habitation. Stool samples from 214 Malaysian …