This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …

1. INTRODUCTION A timely subtitle to this Review focused on conversions of isocyanides at
metal centers could have been “a platinum jubilee of the first metal-mediated reaction …

Catalytic reactions that enable the formation of new bonds to carbon centres play a
pervasive role in the state-of-the-art synthesis of organic molecules and macromolecules. In …

Cyclic structures represent a well-studied structural class due to the novel bonding modes
and reactivity these units possess and the ubiquitous role of cyclic intermediates in a wide …

In this Perspective, we discuss what we perceive to be the continued challenges faced in
catalytic hydrophosphination chemistry. Currently the literature is dominated by catalysts …

While the formation and breaking of transition metal (TM)–carbon bonds plays a pivotal role
in the catalysis of organic compounds, the reactivity of inorganometallic species, that is …

Reactions of an aryldihydroborane with a Pt0 complex lead to a range of novel products,
including complexes with bridging diborene and diborane (3) ligands and a complex with …

Conspectus The rationale to pursue long-term study of any system must be sound. Quick
discoveries and emergent fields are more than temptations. They remind us to ask what are …

The room-temperature reactions of stannocene, Cp* 2Sn, with a range of primary
phosphines, RPH2, result in diphosphanes [RP (H) P (H) R]. The reactions involving Cp …

Exploration of (N3N) ZrNMe2 (1, N3N= N (CH2CH2NSiMe3) 33–) as a catalyst for the cross-
dehydrocoupling or heterodehydrocoupling of silanes and amines suggested silylene …