Conspectus To improve the efficacy of molecular syntheses, researchers wish to capitalize
upon the selective modification of otherwise inert C–H bonds. The past two decades have …

Covering: January to December 2017 This review covers the literature published in 2017 for
marine natural products (MNPs), with 740 citations (723 for the period January to December …

The divergent total syntheses of complex natural products from a common intermediate have
attracted enormous attention in the chemical community in the past few years because it can …

Versatile cobalt catalysis enabled electrochemical C–H activation with allenes. Thus, allene
annulations were accomplished in terms of C–H/N–H functionalizations with excellent levels …

Covering: 2000–2020 The 1, 4-diene motif, also known as a skipped diene, is widespread
across various classes of natural products including alkaloids, fatty acids, terpenoids, and …

This review covers the literature published in 2017 for marine natural products (MNPs), with
740 citations (723 for the period January to December 2017) referring to compounds …

The secondary metabolites that marine sponges create are essential to the advancement of
contemporary medicine and are often employed in clinical settings. Over the past five years …

The control of the selectivity is a central issue in the total synthesis of complex natural
products. In this paper, we report the total synthesis of (±)-keramaphidin B and (±) …

Hydrosilylation of allenes is the addition of a hydrogen atom and a silyl group to a carbon–
carbon double bond of an allene molecule and represents a straightforward and atom …

A unified strategy for nickel (0)‐catalyzed C− H allylations, alkenylations, and dienylations
has been realized through versatile hydroarylations of allenes with ample scope. Thus, an …