Thienothiophenes, dithienothiophenes, and thienoacenes: syntheses, oligomers, polymers, and properties

ME Cinar, T Ozturk - Chemical Reviews, 2015 - ACS Publications
Heterocyclic compounds comprising various biochemical materials are an indispensable
member of our life such as nucleic acids. Moreover, many naturally occurring pigments …

Half-Wave Potential Splittings ΔE1/2 as a Measure of Electronic Coupling in Mixed-Valent Systems: Triumphs and Defeats

RF Winter - Organometallics, 2014 - ACS Publications
This review is a cautionary note against the often purported direct relation between the half-
wave potential splitting Δ E 1/2 (or Δ E°) for stepwise, consecutive electron transfer from …

Molecular electrochemistry of multi-redox functionalized 5-membered heterocycles

D Miesel, A Hildebrandt, H Lang - Current Opinion in Electrochemistry, 2018 - Elsevier
Molecular electrochemistry of multi-redox functionalized 5-membered heterocycles -
ScienceDirect Skip to main contentSkip to article Elsevier logo Journals & Books Search …

Bis-Ferrocenyl-Pyridinediimine Trinuclear Mixed-Valent Complexes with Metal-Binding Dependent Electronic Coupling: Synthesis, Structures, and Redox …

C Carter, Y Kratish, T Jurca, Y Gao… - Journal of the American …, 2020 - ACS Publications
A family of metal dichloride complexes having a bis-ferrocenyl-substituted pyridinediimine
ligand was systematically synthesized ((Fc2PDI) MCl2, M= Mg, Zn, Fe, and Co) and …

2-Nitro-and 4-fluorocinnamaldehyde based receptors as naked-eye chemosensors to potential molecular keypad lock

M Islam, Z Shafiq, F Mabood, HH Shah, V Singh… - Scientific Reports, 2021 - nature.com
New-generation chemosensors desire small organic molecules that are easy to synthesise
and cost-effective. As a new interdisciplinary area of research, the integration of these …

The influence of an ethynyl spacer on the electronic properties in 2, 5-ferrocenyl-substituted heterocycles

U Pfaff, A Hildebrandt, M Korb, H Lang - Polyhedron, 2015 - Elsevier
A series of binuclear complexes based on five-membered heterocycles featuring alkynyl
ferrocenyl groups, 2, 5-(FcCtriple bondC) 2-c C 4 H 2 E (E= NPh, 3a; S, 3b; O, 3c), has been …

Notable differences between oxidized diruthenium complexes bridged by four isomeric diethynyl benzodithiophene ligands

YP Ou, J Zhang, F Zhang, D Kuang, F Hartl, L Rao… - Dalton …, 2016 - pubs.rsc.org
Four new diruthenium complexes [{(η5-C5Me5) Ru (dppe)} 2 (μ-CC–L–CC)] featuring
different bridging isomeric diethynyl benzodithiophenes viz. L= benzo [1, 2-b; 4, 5-b′] …

Sandwich and half-sandwich metal complexes derived from cross-conjugated 3-methylene-penta-1, 4-diynes

KB Vincent, JBG Gluyas, Q Zeng, DS Yufit… - Dalton …, 2017 - pubs.rsc.org
The cross-conjugated ethynyl–vinylidene [Ph2CC (CCH){C (H) CRu (PPh3) 2Cp}] PF6 ([4a]
PF6), and [FcC (H) C (CCH){C (H) CRu (PPh3) 2Cp}] PF6 ([4b] PF6), and ethynyl–alkynyl …

Multiferrocenyl Cobalt‐Based Sandwich Compounds

G Filipczyk, SW Lehrich, A Hildebrandt… - European Journal of …, 2017 - Wiley Online Library
The reaction of FcC≡ C–C≡ CFc [Fc= Fe (η5‐C5H4)(η5‐C5H5)](1) with Co (η5‐C5H5)(CO)
2 (2) afforded ferrocenyl‐functionalized cyclobutadiene and cyclopentadienone cobalt (I) …

1-Cyano-1′-ethynyl-ferrocene: Synthesis and reaction chemistry

F Strehler, M Korb, EA Poppitz, H Lang - Journal of Organometallic …, 2015 - Elsevier
Several consecutive synthetic methodologies for the preparation of Fe (η 5-C 5 H 4 Ctriple
bondN)(η 5-C 5 H 4 Ctriple bondCH)(3) are described. Ferrocene Fe (η 5-C 5 H 4 Ctriple …