[HTML][HTML] Spin state switching in iron coordination compounds
P Gütlich, AB Gaspar, Y Garcia - Beilstein journal of organic …, 2013 - beilstein-journals.org
The article deals with coordination compounds of iron (II) that may exhibit thermally induced
spin transition, known as spin crossover, depending on the nature of the coordinating ligand …
spin transition, known as spin crossover, depending on the nature of the coordinating ligand …
High-pressure studies with x-rays using diamond anvil cells
G Shen, HK Mao - Reports on progress in Physics, 2016 - iopscience.iop.org
Pressure profoundly alters all states of matter. The symbiotic development of ultrahigh-
pressure diamond anvil cells, to compress samples to sustainable multi-megabar pressures; …
pressure diamond anvil cells, to compress samples to sustainable multi-megabar pressures; …
Effects of the electronic spin transitions of iron in lower mantle minerals: Implications for deep mantle geophysics and geochemistry
We have critically reviewed and discussed currently available information regarding the spin
and valence states of iron in lower mantle minerals and the associated effects of the spin …
and valence states of iron in lower mantle minerals and the associated effects of the spin …
Spin transition in magnesiowüstite in Earth's lower mantle
Iron in the major lower mantle (LM) minerals undergoes a high spin (HS) to low spin (LS)
transition at relevant pressures (23–135 GPa). Previous failures of standard first principles …
transition at relevant pressures (23–135 GPa). Previous failures of standard first principles …
Inelastic x-ray scattering by electronic excitations under high pressure
Investigating electronic structure and excitations under extreme conditions gives access to a
rich variety of phenomena. High pressure typically induces behavior such as magnetic …
rich variety of phenomena. High pressure typically induces behavior such as magnetic …
Very low sound velocities in iron‐rich (Mg, Fe) O: Implications for the core‐mantle boundary region
JK Wicks, JM Jackson… - Geophysical Research …, 2010 - Wiley Online Library
The sound velocities of (Mg. 16Fe. 84) O have been measured to 121 GPa at ambient
temperature using nuclear resonant inelastic x‐ray scattering. The effect of electronic …
temperature using nuclear resonant inelastic x‐ray scattering. The effect of electronic …
Anomalous compressibility of ferropericlase throughout the iron spin cross-over
The thermoelastic properties of ferropericlase Mg1− x Fe x O (x= 0.1875) throughout the iron
high-to-low spin cross-over have been investigated by first principles at Earth's lower mantle …
high-to-low spin cross-over have been investigated by first principles at Earth's lower mantle …
Spin transition and equations of state of (Mg, Fe) O solid solutions
We have performed a series of experiments to investigate the compositional effect on the
compression behavior of (Mg, Fe) O solid solutions at high pressure. The in‐situ synchrotron …
compression behavior of (Mg, Fe) O solid solutions at high pressure. The in‐situ synchrotron …
Elasticity of (Mg, Fe) O through the spin transition of iron in the lower mantle
Changes in the electronic configuration of iron at high pressures toward a spin-paired state
within host minerals ferropericlase and silicate perovskite may directly influence the seismic …
within host minerals ferropericlase and silicate perovskite may directly influence the seismic …
Elastic anomalies in a spin-crossover system: Ferropericlase at lower mantle conditions
The discovery of a pressure induced iron-related spin crossover in Mg (1-x) Fe x O
ferropericlase (Fp) and Mg-silicate perovskite, the major phases of Earth's lower mantle, has …
ferropericlase (Fp) and Mg-silicate perovskite, the major phases of Earth's lower mantle, has …