P-Stereogenic phosphorus ligands in asymmetric catalysis

T Imamoto - Chemical reviews, 2024 - ACS Publications
Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …

Transition-metal-catalyzed C–H bond alkylation using olefins: recent advances and mechanistic aspects

D Mandal, S Roychowdhury, JP Biswas… - Chemical Society …, 2022 - pubs.rsc.org
Transition metal catalysis has contributed immensely to C–C bond formation reactions over
the last few decades, and alkylation is no exception. The superiority of such methodologies …

Enantio‐and Regioselective Electrooxidative Cobalt‐Catalyzed C− H/N− H Annulation with Alkenes

QJ Yao, FR Huang, JH Chen, MY Zhong… - Angewandte …, 2023 - Wiley Online Library
In recent years, the merging of electrosynthesis with 3d metal catalyzed C− H activation has
emerged as a sustainable and powerful technique in organic synthesis. Despite the …

Challenges and opportunities in multicatalysis

S Martínez, L Veth, B Lainer, P Dydio - ACS Catalysis, 2021 - ACS Publications
Multicatalysis is an emerging field targeting the development of efficient catalytic
transformations to quickly convert relatively simple starting materials into more complex …

Base‐Promoted Electrochemical CoII‐catalyzed Enantioselective C−H Oxygenation

G Zhou, JH Chen, QJ Yao, FR Huang… - Angewandte Chemie …, 2023 - Wiley Online Library
Metalla‐electrocatalyzed C− H oxygenation represents one of the most straightforward and
sustainable approaches to access valuable oxygenated molecules. Despite the significant …

Synthesis of Axially Chiral Biaryls through Cobalt (II)‐Catalyzed Atroposelective C− H Arylation

YJ Wu, ZK Wang, ZS Jia, JH Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
Highly efficient synthesis of axially chiral biaryl amines through cobalt‐catalyzed
atroposelective C− H arylation using easily accessible cobalt (II) salt and salicyloxazoline …

Cobalt-Catalyzed Enantioselective C–H Annulation of Benzylamines with Alkynes: Application to the Modular and Asymmetric Syntheses of Bioactive Molecules

YJ Wu, JH Chen, MY Teng, X Li, TY Jiang… - Journal of the …, 2023 - ACS Publications
The transition metal-catalyzed enantioselective C–H functionalization strategy has
revolutionized the logic of natural product synthesis. However, previous applications have …

Cobalt-catalyzed enantioselective C–H arylation of indoles

N Jacob, Y Zaid, JCA Oliveira… - Journal of the …, 2022 - ACS Publications
Atropoisomeric (hetero) biaryls are scaffolds with increasing importance in the
pharmaceutical and agrochemical industries. Although it is the most obvious disconnection …

Cobalt-catalyzed enantioselective C–H annulation with alkenes

D Yang, X Zhang, X Wang, XJ Si, J Wang, D Wei… - ACS …, 2023 - ACS Publications
Herein, we disclose an efficient cobalt-catalyzed enantioselective C–H activation and
annulation of benzamides with alkenes. This transformation is facilitated via the …

Cp* Co (III)-catalyzed enantioselective hydroarylation of unactivated terminal alkenes via C–H activation

YH Liu, PP Xie, L Liu, J Fan, ZZ Zhang… - Journal of the …, 2021 - ACS Publications
Enantioselective hydroarylation of unactivated terminal akenes constitutes a prominent
challenge in organic chemistry. Herein, we reported a Cp* Co (III)-catalyzed asymmetric …