Abstract Tiara [5] arenes (T [5] s), a new class of five‐fold symmetric oligophenolic
macrocycles that are not accessible from the addition of formaldehyde to phenol, were …

Although the chemistry of macrocyclic arenes has seen rapid development in recent years,
the synthesis of new macrocyclic arenes from aromatic rings with no directing groups …

Abstract A “rim‐differentiated” pillar [6] arene (RD‐P [6]) was obtained successfully, with the
assistance of a dimeric silver trifluoroacetate template, among eight different constitutional …

Herein, we report a facile and efficient preparation of prism [6] arene (P6) using the
condensation of 2, 6-diethoxy-1, 5-bis (methoxymethyl) naphthalene catalyzed by p …

Through McMurry coupling reaction, three meso‐position functionalized pillar [5] arene
derivatives (H‐1, H‐2, and H‐3) have been successfully prepared by embedding …

Transformation of [15] paracyclophanes ([15] PCP) into fluorophores has been achieved by
embedding tetraphenylethene (TPE) units into their skeletons at the meso-positions. The …

The host–guest properties of [15] paracyclophane ([15] PCPs) are engendered by π-
metalation, which exhibits fantastic regioselectivity toward a macrocyclic molecule. The …

The complexation between tiara [5] arene (T [5]) and silver trifluoroacetate affords a
binuclear metallo-pseudorotaxane on account of multiple endo-cavity AgI η2-arene …

[1 n] Paracyclophane has been known for nearly 40 years, but its derivatives and properties
are understudied in comparison to those of other macrocyclic compounds. By the …

In pursuit of environmental sustainability and energy efficiency, assorted macrocyclic
compounds have recently emerged as crystalline adsorbents for the efficient molecular …