Recent developments for the photoinduced Ar–X bond dissociation reaction

G Qiu, Y Li, J Wu - Organic Chemistry Frontiers, 2016 - pubs.rsc.org
Recent developments in the photochemical carbon–carbon and carbon–heteroatom bond
formation via photoinduced Ar–X bond dissociation are summarized. The transformations …

Transition‐Metal‐Free C3 Arylation of Indoles with Aryl Halides

J Chen, J Wu - Angewandte Chemie International Edition, 2017 - Wiley Online Library
We report an unprecedented transition metal‐free coupling of indoles with aryl halides. The
reaction is promoted by KOtBu and is regioselective for C3 over N. The use of degassed …

[图书][B] Photochemically-generated intermediates in synthesis

A Albini, M Fagnoni - 2013 - books.google.com
Examines the latest applications of photochemistry to generate important intermediates
Presenting the latest breakthroughs in the field of organic photochemistry, this book offers …

Radical Beckmann rearrangement and its application in the formal total synthesis of antimalarial natural product isocryptolepine via C–H activation

PS Mahajan, VT Humne, SD Tanpure… - Organic letters, 2016 - ACS Publications
The Beckmann rearrangement of ketoximes, mediated by ammonium persulfate-dimethyl
sulfoxide as a reagent, has been achieved under neutral conditions. Based on the radical …

Initiation in photoredox C–H functionalization reactions. Is dimsyl anion a key ingredient?

ME Budén, JI Bardagí, M Puiatti… - The Journal of Organic …, 2017 - ACS Publications
Previous studies have reported the arylation of unactivated arenes with ArX, base (KO t Bu
or NaO t Bu), and an organic additive at high temperatures. Recently, we showed that this …

KOtBu-Mediated Aerobic Transition-Metal-Free Regioselective β-Arylation of Indoles: Synthesis of β-(2-/4-Nitroaryl)-indoles

S Kumar, V Rathore, A Verma, CD Prasad… - Organic …, 2015 - ACS Publications
A KO t Bu-mediated intermolecular oxidative C–C coupling of nitroarenes with indoles is
presented in DMSO at room temperature in an open flask. By using this mild and economical …

Copper-Catalyzed N-Benzoylation of Amines via Aerobic C–C Bond Cleavage

W Fan, Y Yang, J Lei, Q Jiang… - The Journal of Organic …, 2015 - ACS Publications
A general copper/air catalytic system for selectively oxidative C–C bond cleavage of 1, 2-
diarylethan-1-one has been developed, giving aromatic aldehydes and N-benzoylation …

Synthesis of Unsymmetrical Diaryl Acetamides, Benzofurans, Benzophenones, and Xanthenes by Transition-Metal-Free Oxidative Cross-Coupling of sp3 and sp2 …

V Rathore, M Sattar, R Kumar… - The Journal of Organic …, 2016 - ACS Publications
A chemo-and regioselective intermolecular sp 3 C–H and sp 2 C–H coupling reaction for C–
C bond formation is described to access unsymmetrical diaryl acetamides under TM-free …

Visible Light Induced Synthesis of 2-Benzoxazolecarboxamides Promoted by a Conjugated Microporous Polymer

Y Zhang, R Wang, C Lu, C Ma, F Wang… - ACS Sustainable …, 2024 - ACS Publications
A new and effective protocol driven by visible light has been introduced for the first time to
synthesize 2-benzoxazolecarboxamides from benzoxazinones and amines in the presence …

Photoinduced synthesis of dibenzofurans: Intramolecular and intermolecular comparative methodologies

P Camargo Solórzano, F Brigante… - The Journal of …, 2018 - ACS Publications
The SRN1 reaction has been used as a powerful tool for the synthesis of heterocycles, and
only a few studies about photoinduced intramolecular cyclization to generate a new C–O …