The acidity of atmospheric particles and clouds

HOT Pye, A Nenes, B Alexander, AP Ault… - Atmospheric …, 2020 - acp.copernicus.org
Acidity, defined as pH, is a central component of aqueous chemistry. In the atmosphere, the
acidity of condensed phases (aerosol particles, cloud water, and fog droplets) governs the …

[HTML][HTML] Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds

A Tilgner, T Schaefer, B Alexander… - Atmospheric …, 2021 - acp.copernicus.org
The acidity of aqueous atmospheric solutions is a key parameter driving both the partitioning
of semi-volatile acidic and basic trace gases and their aqueous-phase chemistry. In addition …

Global impacts of tropospheric halogens (Cl, Br, I) on oxidants and composition in GEOS-Chem

T Sherwen, JA Schmidt, MJ Evans… - Atmospheric …, 2016 - acp.copernicus.org
We present a simulation of the global present-day composition of the troposphere which
includes the chemistry of halogens (Cl, Br, I). Building on previous work within the GEOS …

[HTML][HTML] The role of chlorine in global tropospheric chemistry

X Wang, DJ Jacob, SD Eastham… - Atmospheric …, 2019 - acp.copernicus.org
We present a comprehensive simulation of tropospheric chlorine within the GEOS-Chem
global 3-D model of oxidant–aerosol–halogen atmospheric chemistry. The simulation …

Modeling the processing of aerosol and trace gases in clouds and fogs

B Ervens - Chemical reviews, 2015 - ACS Publications
Aerosol− cloud interactions account for the largest uncertainty in current estimates of
changes in radiative forcing according to the most recent IPCC report. 1 The term “aerosol …

[HTML][HTML] Heterogeneous sulfate aerosol formation mechanisms during wintertime Chinese haze events: air quality model assessment using observations of sulfate …

J Shao, Q Chen, Y Wang, X Lu, P He… - Atmospheric …, 2019 - acp.copernicus.org
Air quality models have not been able to reproduce the magnitude of the observed
concentrations of fine particulate matter (PM 2.5) during wintertime Chinese haze events …

[HTML][HTML] DMS oxidation and sulfur aerosol formation in the marine troposphere: a focus on reactive halogen and multiphase chemistry

Q Chen, T Sherwen, M Evans… - … Chemistry and Physics, 2018 - acp.copernicus.org
The oxidation of dimethyl sulfide (DMS) in the troposphere and subsequent chemical
conversion into sulfur dioxide (SO 2) and methane sulfonic acid (MSA) are key processes for …

Modeling the observed tropospheric BrO background: Importance of multiphase chemistry and implications for ozone, OH, and mercury

JA Schmidt, DJ Jacob, HM Horowitz… - Journal of …, 2016 - Wiley Online Library
Aircraft and satellite observations indicate the presence of ppt (ppt≡ pmol/mol) levels of BrO
in the free troposphere with important implications for the tropospheric budgets of ozone …

Catalytic role of formaldehyde in particulate matter formation

E Dovrou, KH Bates, JM Moch… - Proceedings of the …, 2022 - National Acad Sciences
Formaldehyde (HCHO), the simplest and most abundant carbonyl in the atmosphere,
contributes to particulate matter (PM) formation via two in-cloud processing pathways. First …

Ionic strength enhances the multiphase oxidation rate of sulfur dioxide by ozone in aqueous aerosols: Implications for sulfate production in the marine atmosphere

C Yu, T Liu, D Ge, W Nie, X Chi… - Environmental Science & …, 2023 - ACS Publications
Multiphase oxidation of sulfur dioxide (SO2) by ozone (O3) in alkaline sea salt aerosols is an
important source of sulfate aerosols in the marine atmosphere. However, a recently reported …