Palladium (II)-catalyzed enantioselective reactions using COP catalysts
JS Cannon, LE Overman - Accounts of chemical research, 2016 - ACS Publications
Conspectus Allylic amides, amines, and esters are key synthetic building blocks. Their
enantioselective syntheses under mild conditions is a continuing pursuit of organic synthesis …
enantioselective syntheses under mild conditions is a continuing pursuit of organic synthesis …
Recent advances in the Overman rearrangement: Synthesis of natural products and valuable compounds
In the past decade, the Overman rearrangement, an important C–N bond forming reaction,
has been intensely used in the synthesis of natural products, synthetic intermediates …
has been intensely used in the synthesis of natural products, synthetic intermediates …
Cyclobutadiene metal complexes: a new class of highly selective catalysts. An application to direct reductive amination
A catalyst of a new type, cyclobutadiene complex [(C4Et4) Rh (p-xylene)] PF6, was found to
promote selective reductive amination in the presence of carbon monoxide under mild …
promote selective reductive amination in the presence of carbon monoxide under mild …
Synthesis of rigid chiral C3-symmetric triptycene-based ligands and their application in enantioselective Cu (I)-catalyzed aziridination of chalcones
I Kisets, D Gelman - Journal of Organometallic Chemistry, 2021 - Elsevier
The design and synthesis of C 3-symmetric or pseudo-C 3-symmetric ligands present a
particular challenge because the molecular frames available for fitting C 3 symmetry are …
particular challenge because the molecular frames available for fitting C 3 symmetry are …
Exploring anagostic interactions in 5, 15-porphodimethene metal complexes
Using a metal templating strategy, 5, 15-porphodimethene metal complexes were
synthesized and their structure confirmed by single crystal X-ray analysis. The anagostic …
synthesized and their structure confirmed by single crystal X-ray analysis. The anagostic …
Palladacycles based on 8-aminoquinoline carboxamides of cobalt and iron sandwich compounds and a new method to α-alkylate Cp rings of metal sandwich …
Reactions of {η5-C5H4 [C (O) Cl]} Co (η4-C4Ph4) and {η5-C5H4 [C (O) Cl]} Fe (η5-Cp) with
8-aminoquinoline resulted in cobalt and iron sandwich derived carboxamides. The reaction …
8-aminoquinoline resulted in cobalt and iron sandwich derived carboxamides. The reaction …
Chemistry of the highly stable hindered cobalt sandwich compound (η5-Cp) Co (η4-C4Ph4) and its derivatives
A comprehensive review on the synthesis, reactions and applications centered on the highly
stable and sterically hindered cobalt sandwich compound (η 5-Cp) Co (η 4-C 4 Ph 4) is …
stable and sterically hindered cobalt sandwich compound (η 5-Cp) Co (η 4-C 4 Ph 4) is …
Recent studies in metal-cyclopentadienyl and metal-arene chemistry
MD Rausch - Pure and Applied Chemistry Fifth, 1972 - degruyter.com
The formation, chemical reactivity, and spectral properties of a variety of new rr-bonded and
cr-bonded organic derivatives of the transition metals are described. The Effective Atomic …
cr-bonded organic derivatives of the transition metals are described. The Effective Atomic …
Chiral multidentate oxazoline ligands based on cyclophosphazene cores: synthesis, characterization and complexation studies
Chiral oxazoline based bi and hexadentate ligands built on cyclophosphazene cores have
been synthesized and characterized.(NPPh2) 2 [NP (m-OC6H4C (O) OCH3) 2](1) was …
been synthesized and characterized.(NPPh2) 2 [NP (m-OC6H4C (O) OCH3) 2](1) was …
An Improved Protocol for the Synthesis of [(η4-C4R4)Co(η5-C5H5)] Complexes
The reaction of bulky alkynes C2R2 with (η5-C5H5) Co (CO)(dimethyl fumarate) under
microwave irradiation provides complexes of the type [(η4-C4R4) Co (η5-C5H5)] in good to …
microwave irradiation provides complexes of the type [(η4-C4R4) Co (η5-C5H5)] in good to …