Two-dimensional polymers and polymerizations

AM Evans, MJ Strauss, AR Corcos, Z Hirani… - Chemical …, 2021 - ACS Publications
Synthetic chemists have developed robust methods to synthesize discrete molecules, linear
and branched polymers, and disordered cross-linked networks. However, two-dimensional …

Scanning probe microscopy

K Bian, C Gerber, AJ Heinrich, DJ Müller… - Nature Reviews …, 2021 - nature.com
Scanning probe microscopy (SPM), a key invention in nanoscience, has by now been
extended to a wide spectrum of basic and applied fields. Its application to basic science led …

Biphenylene network: A nonbenzenoid carbon allotrope

Q Fan, L Yan, MW Tripp, O Krejčí, S Dimosthenous… - Science, 2021 - science.org
The quest for planar sp2-hybridized carbon allotropes other than graphene, such as
graphenylene and biphenylene networks, has stimulated substantial research efforts …

Design of local atomic environments in single‐atom electrocatalysts for renewable energy conversions

T Sun, S Mitchell, J Li, P Lyu, X Wu… - Advanced …, 2021 - Wiley Online Library
Single‐atom electrocatalysts (SAECs) have recently attracted tremendous research interest
due to their often remarkable catalytic responses, unmatched by conventional catalysts. The …

[HTML][HTML] On-surface synthesis of a doubly anti-aromatic carbon allotrope

Y Gao, F Albrecht, I Rončević, I Ettedgui, P Kumar… - Nature, 2023 - nature.com
Synthetic carbon allotropes such as graphene, carbon nanotubes and fullerenes have
revolutionized materials science and led to new technologies. Many hypothetical carbon …

An sp-hybridized molecular carbon allotrope, cyclo [18] carbon

K Kaiser, LM Scriven, F Schulz, P Gawel, L Gross… - Science, 2019 - science.org
Carbon allotropes built from rings of two-coordinate atoms, known as cyclo [n] carbons, have
fascinated chemists for many years, but until now they could not be isolated or structurally …

Real-space imaging of anisotropic charge of σ-hole by means of Kelvin probe force microscopy

B Mallada, A Gallardo, M Lamanec, B De La Torre… - Science, 2021 - science.org
An anisotropic charge distribution on individual atoms, such as σ-holes, may strongly affect
the material and structural properties of systems. However, the spatial resolution of such …

Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis

S Clair, DG de Oteyza - Chemical reviews, 2019 - ACS Publications
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …

[HTML][HTML] Production and processing of graphene and related materials

C Backes, AM Abdelkader, C Alonso… - 2D …, 2020 - iopscience.iop.org
We present an overview of the main techniques for production and processing of graphene
and related materials (GRMs), as well as the key characterization procedures. We adopt …

Topological frustration induces unconventional magnetism in a nanographene

S Mishra, D Beyer, K Eimre, S Kezilebieke… - Nature …, 2020 - nature.com
The chemical versatility of carbon imparts manifold properties to organic compounds, where
magnetism remains one of the most desirable but elusive. Polycyclic aromatic hydrocarbons …