Chiral sulfinyl compounds, sulfoxides, sulfoximines, sulfinamides, and other derivatives, play
an important role in asymmetric synthesis as versatile auxiliaries, ligands, and catalysts …

Sulfonimidamides are intriguing new motifs for medicinal and agrochemistry, and provide
attractive bioisosteres for sulfonamides. However, there remain few operationally simple …

Historically, sulfoximines, sulfondiimines and sulfonimidamides have been neglected
pharmacophores in drug discovery even though they offer very interesting properties. This …

Due to their three-dimensional structure, chemical and metabolic stability, polarity, and
hydrogen-bonding ability, sulfonamides occupy a privileged position among the functional …

Sulfoximines and sulfonimidamides are promising compounds for medicinal and
agrochemistry. As monoaza analogues of sulfones and sulfonamides, respectively, they …

A sustainable, mechanochemical procedure for the synthesis of sulfur (VI) fluorides starting
from readily available sulfur (VI) 2-methylimidazoles as stable S (VI) precursors has been …

Sulfonimidamides present exciting opportunities as chiral isosteres of sulfonamides, with
potential for additional directional interactions. Here, we present the first modular …

The development of NH transfer reactions using hypervalent iodine and simple sources of
ammonia has facilitated the synthesis of sulfoximines and sulfonimidamides for applications …

Sulfinamides are versatile, synthetically useful intermediates, and final motifs. Traditional
methods to synthesize sulfinamides generally require substrates with preinstalled sulfur …

The occurrence of sulfoximines and sulfonimidoyl groups in biologically active molecules
within pharmaceuticals and agrochemicals has notably increased in the past decade. This …