The Green ChemisTREE: 20 years after taking root with the 12 principles

HC Erythropel, JB Zimmerman, TM de Winter… - Green chemistry, 2018 - pubs.rsc.org
The field of Green Chemistry has seen many scientific discoveries and inventions during the
20 years since the 12 Principles were first published. Inspired by tree diagrams that illustrate …

Direct (hetero) arylation polymerization: simplicity for conjugated polymer synthesis

JR Pouliot, F Grenier, JT Blaskovits, S Beaupré… - Chemical …, 2016 - ACS Publications
Direct (hetero) arylation polymerization (DHAP) has recently been established as an
environmentally benign method for the preparation of conjugated polymers. This synthetic …

Manganese‐Catalyzed C− H Alkynylation: Expedient Peptide Synthesis and Modification

Z Ruan, N Sauermann, E Manoni… - Angewandte …, 2017 - Wiley Online Library
Abstract Manganese (I)‐catalyzed C− H alkynylations with organic halides occurred with
unparalleled substrate scope, and thus enabled step‐economical C− H functionalizations …

Challenges to the success of commercial organic photovoltaic products

M Moser, A Wadsworth, N Gasparini… - Advanced Energy …, 2021 - Wiley Online Library
Recent advances in the development of organic photovoltaic (OPV) materials has led to
significant improvements in device performance; now closing in on the 20% efficiency …

Design strategies of n-type conjugated polymers for organic thin-film transistors

Y Sui, Y Deng, T Du, Y Shi, Y Geng - Materials Chemistry Frontiers, 2019 - pubs.rsc.org
Significant progress in n-type conjugated polymers (CPs) for organic thin-film transistors
(OTFTs), which are required in making complementary metal oxide semiconductor (CMOS) …

Tin-free direct C–H arylation polymerization for high photovoltaic efficiency conjugated copolymers

AS Dudnik, TJ Aldrich, ND Eastham… - Journal of the …, 2016 - ACS Publications
A new and highly regioselective direct C–H arylation polymerization (DARP) methodology
enables the reproducible and sustainable synthesis of high-performance π-conjugated …

Direct C–H arylation: A “Greener” approach towards facile synthesis of organic semiconducting molecules and polymers

H Bohra, M Wang - Journal of Materials Chemistry A, 2017 - pubs.rsc.org
Organic π-conjugated small molecules and polymers, owing to their light weight, solution
processability, mechanical flexibility, and large synthetic variety of finely tunable structures …

Reactivity-controlling factors in carboxylate-assisted C–H activation under 4d and 3d transition metal catalysis

T Rogge, JCA Oliveira, R Kuniyil, L Hu… - ACS …, 2020 - ACS Publications
Detailed density functional theory calculations provide valuable insight into reactivity-
controlling factors in transition metal-catalyzed C–H activation by carboxylate assistance …

Triarylamine/Bithiophene Copolymer with Enhanced Quinoidal Character as Hole‐Transporting Material for Perovskite Solar Cells

HS Lin, T Doba, W Sato, Y Matsuo… - Angewandte Chemie …, 2022 - Wiley Online Library
Polytriarylamine is a popular hole‐transporting materials (HTMs) despite its suboptimal
conductivity and significant recombination at the interface in a solar cell setup. Having noted …

Semiconducting polymers based on isoindigo and its derivatives: synthetic tactics, structural modifications, and applications

X Wei, W Zhang, G Yu - Advanced Functional Materials, 2021 - Wiley Online Library
The past few decades have witnessed the tremendous development of semiconducting
polymers in electronic applications, which is inextricably related to the diversity of polymer …