Recent progress in the science of complex coacervation
Complex coacervation is an associative, liquid–liquid phase separation that can occur in
solutions of oppositely-charged macromolecular species, such as proteins, polymers, and …
solutions of oppositely-charged macromolecular species, such as proteins, polymers, and …
Saloplastics: processing compact polyelectrolyte complexes
P Schaaf, JB Schlenoff - Advanced Materials, 2015 - Wiley Online Library
Polyelectrolyte complexes (PECs) are prepared by mixing solutions of oppositely charged
polyelectrolytes. These diffuse, amorphous precipitates may be compacted into dense …
polyelectrolytes. These diffuse, amorphous precipitates may be compacted into dense …
Driving forces for oppositely charged polyion association in aqueous solutions: enthalpic, entropic, but not electrostatic
J Fu, JB Schlenoff - Journal of the American Chemical Society, 2016 - ACS Publications
Driving forces for association between oppositely charged biological or synthetic polymers
in aqueous solution have long been identified as electrostatic in origin. This attraction is …
in aqueous solution have long been identified as electrostatic in origin. This attraction is …
The polyelectrolyte complex/coacervate continuum
Q Wang, JB Schlenoff - Macromolecules, 2014 - ACS Publications
Stoichiometric polyelectrolyte complexes (PECs) of the strong polyelectrolytes poly
(styrenesulfonate)(PSS) and poly (diallyldimethylammonium)(PDADMA) were dissociated …
(styrenesulfonate)(PSS) and poly (diallyldimethylammonium)(PDADMA) were dissociated …
Structure and rheology of polyelectrolyte complex coacervates
Scattering investigations of the structure and chain conformations, and the rheological
properties of polyelectrolyte complexes (PECs) comprising model polyelectrolytes are …
properties of polyelectrolyte complexes (PECs) comprising model polyelectrolytes are …
An overview of coacervates: The special disperse state of amphiphilic and polymeric materials in solution
Individual amphiphiles, polymers, and colloidal dispersions influenced by temperature, pH,
and environmental conditions or interactions between their oppositely charged pairs in …
and environmental conditions or interactions between their oppositely charged pairs in …
Molecular conformation of polyelectrolytes inside Layer-by-Layer assembled films
P Gutfreund, C Higy, G Fragneto, M Tschopp… - Nature …, 2023 - nature.com
Among all methods available for the preparation of multifunctional nanostructured composite
materials with remarkable functional properties, Layer-by-Layer (LbL) assembly is currently …
materials with remarkable functional properties, Layer-by-Layer (LbL) assembly is currently …
A molecular thermodynamic model of complexation in mixtures of oppositely charged polyelectrolytes with explicit account of charge association/dissociation
Into an extended Voorn–Overbeek (EVO) free energy model of polyelectrolyte (PE)
complexation and phase behavior, we incorporate three classes of short-ranged …
complexation and phase behavior, we incorporate three classes of short-ranged …
Control of dynamics in polyelectrolyte complexes by temperature and salt
M Yang, J Shi, JB Schlenoff - Macromolecules, 2019 - ACS Publications
The linear viscoelastic responses for a series of polyelectrolyte complexes, PECs, made
from pairs of poly [3-(methacryloylamino) propyltrimethylammonium chloride], a polycation …
from pairs of poly [3-(methacryloylamino) propyltrimethylammonium chloride], a polycation …
The influence of ionic strength and mixing ratio on the colloidal stability of PDAC/PSS polyelectrolyte complexes
Y Zhang, E Yildirim, HS Antila, LD Valenzuela… - Soft Matter, 2015 - pubs.rsc.org
Polyelectrolyte complexes (PECs) form by mixing polycation and polyanion solutions
together, and have been explored for a variety of applications. One challenge for PEC …
together, and have been explored for a variety of applications. One challenge for PEC …