Organic thermally activated delayed fluorescence (TADF) compounds used in photocatalysis

MA Bryden, E Zysman-Colman - Chemical Society Reviews, 2021 - pubs.rsc.org
Organic compounds that show Thermally Activated Delayed Fluorescence (TADF) have
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …

Reactive species in advanced oxidation processes: Formation, identification and reaction mechanism

J Wang, S Wang - Chemical Engineering Journal, 2020 - Elsevier
The formation, identification and reaction mechanism of reactive species in various
advanced oxidation processes (AOPs) are crucial for understanding the principles of AOPs …

Visible light-driven radical-mediated C–C bond cleavage/functionalization in organic synthesis

XY Yu, JR Chen, WJ Xiao - Chemical Reviews, 2020 - ACS Publications
Thermal C–C bond cleavage reactions allow the construction of structurally diverse
molecular skeletons via predictable and efficient bond reorganizations. Visible light …

Visible light photocatalysis in the late-stage functionalization of pharmaceutically relevant compounds

R Cannalire, S Pelliccia, L Sancineto… - Chemical Society …, 2021 - pubs.rsc.org
The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …

Direct decarboxylative Giese reactions

DM Kitcatt, S Nicolle, AL Lee - Chemical Society Reviews, 2022 - pubs.rsc.org
The quest to find milder and more sustainable methods to generate highly reactive, carbon-
centred intermediates has led to a resurgence of interest in radical chemistry. In particular …

Photoactive electron donor–acceptor complex platform for Ni-mediated C (sp 3)–C (sp 2) bond formation

LM Kammer, SO Badir, RM Hu, GA Molander - Chemical Science, 2021 - pubs.rsc.org
A dual photochemical/nickel-mediated decarboxylative strategy for the assembly of C (sp3)–
C (sp2) linkages is disclosed. Under light irradiation at 390 nm, commercially available and …

Three-component olefin dicarbofunctionalization enabled by nickel/photoredox dual catalysis

MW Campbell, JS Compton, CB Kelly… - Journal of the …, 2019 - ACS Publications
An intermolecular, photocatalytic dicarbofunctionalization (DCF) of olefins enabled by the
merger of Giese-type addition with Ni/photoredox dual catalysis has been realized …

Redox-neutral photocatalytic cyclopropanation via radical/polar crossover

JP Phelan, SB Lang, JS Compton… - Journal of the …, 2018 - ACS Publications
A benchtop stable, bifunctional reagent for the redox-neutral cyclopropanation of olefins has
been developed. Triethylammonium bis (catecholato) iodomethylsilicate can be readily …

Alkenyl boronates: synthesis and applications

J Carreras, A Caballero… - Chemistry–An Asian …, 2019 - Wiley Online Library
Organoboron compounds have become one of the most versatile building blocks in organic
synthesis owing to their accessible and efficient conversion into many different functional …

Utilization of C(sp3)‐Carboxylic Acids and Their Redox‐Active Esters in Decarboxylative Carbon−Carbon Bond Formation

S Karmakar, A Silamkoti, NA Meanwell… - Advanced Synthesis …, 2021 - Wiley Online Library
Over the last several years, radical‐mediated decarboxylative cross‐coupling reactions
employing alkyl carboxylic acids have emerged as a powerful tool for the regiospecific …