Beyond triphosphates: reagents and methods for chemical oligophosphorylation

SM Shepard, HJ Jessen… - Journal of the American …, 2022 - ACS Publications
Oligophosphates play essential roles in biochemistry, and considerable research has been
directed toward the synthesis of both naturally occurring oligophosphates and their synthetic …

The aryne phosphate reaction

TM Haas, S Wiesler, T Dürr‐Mayer… - Angewandte Chemie …, 2022 - Wiley Online Library
Condensed phosphates are a critically important class of molecules in biochemistry. Non‐
natural analogues are important for various applications, such as single‐molecule real‐time …

Pentaphosphorylation via the Anhydride of Dihydrogen Pentametaphosphate: Access to Nucleoside Hexa-and Heptaphosphates and Study of Their Interaction with …

G Park, EC Wralstad, N Faginas-Lago, K Qian… - ACS Central …, 2024 - ACS Publications
Pentametaphosphate is the little studied cyclic pentamer of the metaphosphate ion,[PO3] 55–
. We show that the doubly protonated form of this pentamer can be selectively dehydrated to …

Non‐Hydrolysable Analogues of Cyclic and Branched Condensed Phosphates: Chemistry and Chemical Proteomics

T Dürr‐Mayer, A Schmidt, S Wiesler… - … A European Journal, 2023 - Wiley Online Library
Studies into the biology of condensed phosphates almost exclusively cover linear
polyphosphates. However, there is evidence for the presence of cyclic polyphosphates …

From Elusive Monomeric Metaphosphates to Oligomeric Metaphosphate Reagents: New Avenue to Halogen-free Phosphorylation of Biomolecules

VD Romanenko - Current Organic Chemistry, 2022 - ingentaconnect.com
This perspective highlights a new environmentally benign strategy for the introduction of
phosphate functionality into organic substrates via activated cyclic oligometaphosphates …

3 Nucleotides

OP HO, P HO, B HO - degruyter.com
Nucleotides are phosphoric acid esters of nucleosides. Any of the sugar hydroxyl functions
may be phosphorylated. The name of nucleotide is derived from the name of nucleoside by …

Activated Phosphate Reagents for the Synthesis of Functionalized Oligophosphates

SM Shepard - 2021 - dspace.mit.edu
Oligophosphates play essential roles in biochemistry, and considerable research has been
directed towards the synthesis of both naturally occurring oligophosphates and their …