Lanthanide supramolecular chemistry is a fast growing and intriguing research field due to
the unique photophysical, magnetic, and coordination properties of lanthanide ions (LnIII) …

The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Substituted dysprosocenium complexes of the type [Dy (Cp R) 2]+ exhibit slow magnetic
relaxation at cryogenic temperatures and have emerged as top-performing single-molecule …

Lanthanides have been investigated extensively for potential applications in quantum
information processing and high-density data storage at the molecular and atomic scale …

Toward promising candidates of quantum information processing, the rapid development of
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …

The unique electronic and magnetic properties of lanthanide molecular complexes place
them at the forefront of the race toward high-temperature single-molecule magnets and …

The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …

We report a monometallic dysprosium complex,[Dy (OtBu) 2 (py) 5][BPh4](5), that shows the
largest effective energy barrier to magnetic relaxation of Ueff= 1815 (1) K. The massive …