Transition‐metal‐catalyzed cross‐coupling reactions are central to many organic synthesis
methodologies. Traditionally, Pd, Ni, Cu, and Fe catalysts are used to promote these …

The application of atomically precise nanocluster-based catalysts in organic synthesis has
been practiced for decades. Such nanoclusters have been used as ideal catalysts as their …

Metal or metal cluster-doped zeolites catalyse a wide variety of reactions. In this work, a
coupling reaction between bromobenzene and phenylboronic acid to yield biphenyl with the …

Ligand protected atom-precise gold-based catalysts have been utilized in many essential
chemical processes, but their mechanism and the fate of the catalyst during reaction are still …

Carbon–carbon bond reductive elimination from gold (III) complexes are known to be very
slow and require high temperatures. Recently, Toste and co‐workers have demonstrated …

Newly synthesized blue-emitting few-atom copper nanoclusters (CuNCs) have been
successfully utilized for catalyzing C (sp2)–C (sp2) and C (sp2)–N (sp3) bond formations …

The geometrical properties of 4‐Aminopyridine and the transition metal clusters M4 (M= Co,
Ni and Cu) adsorbed 4‐Aminopyridine were examined using DFT/B3LYP/6‐31G*/LANL2DZ …

Supported gold nanoparticles on metal oxides (1 mol%) catalyze for the first time the cis-
selective disilylation of terminal alkynes by 1, 2-disilanes in isolated yields up to 94%. It is …

Kinetic and thermodynamic preferences for the reductive elimination of Caryl− CF3, Caryl−
X, Caryl− P, and CF3− X bonds and competitive phosphine dissociation from a series of AuIII …

The exploration of low-cost, efficient, environmentally safe, and selective catalysts for the
activation of carbon–halogen bonds has become an important and challenging topic in …