Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …

The chemistry of heterocyclic compounds has traditionally been and remains a bright area of
chemical science in Russia. This is due to the fact that many heterocycles find the widest …

Herein, we report a hydrodefluorination reaction of polyfluoroarenes catalyzed by
bismuthinidenes, Phebox-Bi (I) and OMe-Phebox-Bi (I). Mechanistic studies on the …

The palladium‐catalyzed difluoroalkylation of aryl boronic acids with
bromodifluoromethylphosphonate, bromodifluoroacetate, and further derivatives has been …

A Ni-catalyzed borylation via C–F activation is described. This protocol is distinguished by a
wide scope, including unactivated fluoroarenes, without compromising its efficiency and …

Bismuth has recently been shown to be able to maneuver between different oxidation states,
enabling access to unique redox cycles that can be harnessed in the context of organic …

C–F bond activation is currently considered to be “a hot topic” in many different but
interconnected fields of research, due to its inherent inertness and unique properties. While …

The direct employment of polyfluoroarenes and gem-difluoroalkenes as building blocks is
regarded as one of the most effective and straightforward strategies for the introduction of …

The new millennium has witnessed the rapid development of synthetic organofluorine
chemistry all over the world, and chemists in China have made significant contributions in …

The copper‐catalyzed stereoselective defluorinative borylation and silylation of gem‐
difluoroalkenes was developed. The protocol led to the exclusive formation of Z type …