Oxygen Evolution/Reduction Reaction Catalysts: From In Situ Monitoring and Reaction Mechanisms to Rational Design

Y Zhao, DP Adiyeri Saseendran, C Huang… - Chemical …, 2023 - ACS Publications
The oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are core steps of
various energy conversion and storage systems. However, their sluggish reaction kinetics …

Artificial photosynthesis: opportunities and challenges of molecular catalysts

B Zhang, L Sun - Chemical Society Reviews, 2019 - pubs.rsc.org
Molecular catalysis plays an essential role in both natural and artificial photosynthesis (AP).
However, the field of molecular catalysis for AP has gradually declined in recent years …

Water oxidation catalysts for artificial photosynthesis

S Ye, C Ding, M Liu, A Wang, Q Huang… - Advanced …, 2019 - Wiley Online Library
Water oxidation is the primary reaction of both natural and artificial photosynthesis.
Developing active and robust water oxidation catalysts (WOCs) is the key to constructing …

Design of molecular water oxidation catalysts with earth-abundant metal ions

M Kondo, H Tatewaki, S Masaoka - Chemical Society Reviews, 2021 - pubs.rsc.org
The four-electron oxidation of water (2H2O→ O2+ 4H++ 4e−) is considered the main
bottleneck in artificial photosynthesis. In nature, this reaction is catalysed by a Mn4CaO5 …

The development of molecular water oxidation catalysts

R Matheu, P Garrido-Barros, M Gil-Sepulcre… - Nature Reviews …, 2019 - nature.com
There is an urgent need to transition from fossil fuels to solar fuels—not only to lower CO2
emissions that cause global warming but also to ration fossil resources. Splitting H2O with …

Bioinspired Trinuclear Copper Catalyst for Water Oxidation with a Turnover Frequency up to 20000 s–1

QF Chen, ZY Cheng, RZ Liao… - Journal of the American …, 2021 - ACS Publications
Solar-powered water splitting is a dream reaction for constructing an artificial photosynthetic
system for producing solar fuels. Natural photosystem II is a prototype template for research …

Heterobimetallic NiFe cooperative molecular water oxidation catalyst

HT Zhang, YH Guo, Y Xiao, HY Du… - Angewandte Chemie …, 2023 - Wiley Online Library
We reported herein the development of heterobimetallic NiFe molecular platform to
understand NiFe synergistic effect in water oxidation catalysis. Compared to homonuclear …

Intramolecular proton transfer boosts water oxidation catalyzed by a Ru complex

R Matheu, MZ Ertem, J Benet-Buchholz… - Journal of the …, 2015 - ACS Publications
We introduce a new family of complexes with the general formula [Ru n (tda)(py) 2] m+(n= 2,
m= 0, 1; n= 3, m= 1, 2+; n= 4, m= 2, 3 2+), with tda2–being [2, 2′: 6′, 2 ″-terpyridine]-6, 6 …

How to make an efficient and robust molecular catalyst for water oxidation

P Garrido-Barros, C Gimbert-Suriñach… - Chemical Society …, 2017 - pubs.rsc.org
Energy has been a central subject for human development from Homo erectus to date. The
massive use of fossil fuels during the last 50 years has generated a large CO2 concentration …

O–O bond formation mechanisms during the oxygen evolution reaction over synthetic molecular catalysts

XP Zhang, HY Wang, H Zheng, W Zhang… - Chinese Journal of …, 2021 - Elsevier
Water oxidation is one of the most important reactions in natural and artificial energy
conversion schemes. In nature, solar energy is converted to chemical energy via water …