Toolbox for distal C–H bond functionalizations in organic molecules

SK Sinha, S Guin, S Maiti, JP Biswas, S Porey… - Chemical …, 2021 - ACS Publications
Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …

Homogeneous gold-catalyzed oxidation reactions

Z Zheng, X Ma, X Cheng, K Zhao, K Gutman… - Chemical …, 2021 - ACS Publications
Homogeneous gold catalysis has experienced extraordinary development since the dawn of
this millennium. Oxidative gold catalysis is a vibrant and fertile subfield and has over the …

Recent advances in gold (III) chemistry: structure, bonding, reactivity, and role in homogeneous catalysis

L Rocchigiani, M Bochmann - Chemical Reviews, 2020 - ACS Publications
Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Homogeneous and heterogeneous gold catalysis for materials science

CM Hendrich, K Sekine, T Koshikawa… - Chemical …, 2020 - ACS Publications
Often stoichiometric amounts of gold find use in materials science; occasionally gold is even
used as a support. This review discusses the contributions of gold catalysis, both …

Controlling Reactivity and Selectivity in the Nondirected C–H Activation of Arenes with Palladium

S Kaltenberger, M van Gemmeren - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Aromatic structures are widespread motifs throughout organic chemistry, and C–
H activation has been recognized as a major tool for enabling their sustainable and efficient …

Arene diversification through distal C(sp2)−H functionalization

U Dutta, S Maiti, T Bhattacharya, D Maiti - Science, 2021 - science.org
BACKGROUND Organic synthetic chemistry has facilitated the production of medicines,
agrochemicals, food, polymers, dyes, and more through step-and atom-economical …

Installing the “magic methyl”–C–H methylation in synthesis

D Aynetdinova, MC Callens, HB Hicks… - Chemical Society …, 2021 - pubs.rsc.org
The selective and efficient C–H methylation of sp2 and sp3 carbon centres has become a
powerful transformation in the synthetic toolbox. Due to the potential for profound changes to …

Advances in synthetic applications of hypervalent iodine compounds

A Yoshimura, VV Zhdankin - Chemical reviews, 2016 - ACS Publications
The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

Traditional and sustainable approaches for the construction of C–C bonds by harnessing C–H arylation

J Grover, G Prakash, N Goswami, D Maiti - Nature Communications, 2022 - nature.com
Biaryl scaffolds are found in natural products and drug molecules and exhibit a wide range
of biological activities. In past decade, the transition metal-catalyzed C–H arylation reaction …

Construction of medium-sized rings by gold catalysis

RL Reyes, T Iwai, M Sawamura - Chemical Reviews, 2020 - ACS Publications
Compounds having cyclic molecular frameworks are highly regarded for their abundance
and diverse utilities. In particular, medium-sized carbocycles and heterocycles exist in a …