Fluorochemicals from fluorspar via a phosphate-enabled mechanochemical process that bypasses HF
C Patel, E André-Joyaux, JA Leitch… - Science, 2023 - science.org
All fluorochemicals—including elemental fluorine and nucleophilic, electrophilic, and radical
fluorinating reagents—are prepared from hydrogen fluoride (HF). This highly toxic and …
fluorinating reagents—are prepared from hydrogen fluoride (HF). This highly toxic and …
Covalent drug discovery using sulfur (VI) fluoride exchange warheads
Introduction Covalent drug discovery has traditionally focused on targeting cysteine, but the
amino acid is often absent in protein binding sites. This review makes the case to move …
amino acid is often absent in protein binding sites. This review makes the case to move …
Synthesis of sulfonyl, sulfonimidoyl, and sulfoxyl fluorides under solvent-free mechanochemical conditions in a mixer mill by imidazole-to-fluorine exchange
MT Passia, MM Amer, J Demaerel… - … Sustainable Chemistry & …, 2023 - ACS Publications
A sustainable, mechanochemical procedure for the synthesis of sulfur (VI) fluorides starting
from readily available sulfur (VI) 2-methylimidazoles as stable S (VI) precursors has been …
from readily available sulfur (VI) 2-methylimidazoles as stable S (VI) precursors has been …
Asymmetric synthesis of sulfoximines, sulfonimidoyl fluorides and sulfonimidamides enabled by an enantiopure bifunctional S (VI) reagent
An increased interest to expand three-dimensional chemical space for the design of new
materials and medicines has created a demand for isosteric replacement groups of …
materials and medicines has created a demand for isosteric replacement groups of …
Molecules Featuring the Azaheterocycle Moiety toward the Application of Flame-Retardant Polymers
S Lu, S Chen, L Luo, Y Yang, J Wang… - ACS Chemical Health …, 2023 - ACS Publications
Flame retardancy is a desirable property of polymer materials, and the molecular design of
novel flame-retardant structures considers three main aspects:(i) the chemical structure …
novel flame-retardant structures considers three main aspects:(i) the chemical structure …
Selective Synthesis of Sulfonamides and Sulfenamides from Sodium Sulfinates and Amines
R Feng, ZY Li, YJ Liu, ZB Dong - The Journal of Organic …, 2024 - ACS Publications
An effective method was explored for the selective synthesis of sulfonamides and
sulfenamides using sodium sulfinates and amines as starting materials. This method offers …
sulfenamides using sodium sulfinates and amines as starting materials. This method offers …
The Modular Synthesis of Sulfondiimidoyl Fluorides and their Application to Sulfondiimidamide and Sulfondiimine Synthesis
M Ding, C Bell, MC Willis - Angewandte Chemie, 2024 - Wiley Online Library
A modular synthesis of sulfondiimidoyl fluorides—the double aza‐analogues of sulfonyl
fluorides—allowing variation of the carbon and both nitrogen‐substituents is reported. The …
fluorides—allowing variation of the carbon and both nitrogen‐substituents is reported. The …
Rapid aminations of functionalized aryl fluorosulfates in water
BH Lipshutz, K Dismuke Rodriguez… - Angewandte Chemie … - Wiley Online Library
Aryl fluorosulfates of varying complexities have been used in amination reactions in water
using a new Pd oxidative addition complex (OAC‐1) developed specifically to match the …
using a new Pd oxidative addition complex (OAC‐1) developed specifically to match the …
Switching to the non-PFAS-containing fluorosulfate leaving group, together with a Pd oxidative addition complex: rapid aminations of functionalized aromatics in water
K Iyer, KD Rodriguez, R Lammert, J Yirak, J Saunders… - 2024 - chemrxiv.org
Aryl fluorosulfates of varying complexities have been used in amination reactions in water
using a new Pd oxidative addition complex (OAC) developed specifically to match the needs …
using a new Pd oxidative addition complex (OAC) developed specifically to match the needs …
Investigations of one-pot synthetic transformations mediated by sulfuryl fluoride and thionyl fluoride
TG Bolduc - 2023 - open.library.ubc.ca
The development of mild, selective, efficient, and economical chemical transformations is a
foundation of modern synthetic organic chemistry. These chemical processes may be …
foundation of modern synthetic organic chemistry. These chemical processes may be …