Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Cross-dehydrogenative coupling: a sustainable reaction for C–C bond formations

T Tian, Z Li, CJ Li - Green Chemistry, 2021 - pubs.rsc.org
We are entering an era that emphasizes greenness and sustainability. Based on such a
philosophy, it is critical to uncover novel and original sustainable reaction modes for future …

Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization

X Wang, J He, YN Wang, Z Zhao, K Jiang… - Chemical …, 2024 - ACS Publications
Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

Cross-dehydrogenative coupling involving benzylic and allylic C–H bonds

I Bosque, R Chinchilla, JC Gonzalez-Gomez… - Organic Chemistry …, 2020 - pubs.rsc.org
In recent years, the cross-dehydrogenative coupling (CDC) has demonstrated to be a
powerful synthetic tool to form C–C bonds from two C–H bonds. This high atom-economic …

Cross‐Dehydrogenative Alkynylation: A Powerful Tool for the Synthesis of Internal Alkynes

JS Zhang, L Liu, T Chen, LB Han - ChemSusChem, 2020 - Wiley Online Library
Alkynes are among the most fundamentally important organic compounds and are widely
used in synthetic chemistry, biochemistry, and materials science. Thus, the development of …

Copper‐Catalyzed Cross‐Dehydrogenative Coupling Reactions

CMA Afsina, T Aneeja, M Neetha… - European Journal of …, 2021 - Wiley Online Library
Copper‐catalyzed organic reactions have received wide attention due to the high relative
abundance of copper, its cheap price, low toxicity, eco‐friendliness, sustainable nature, and …

Regioselective and Redox‐Neutral Cp*IrIII‐Catalyzed Allylic C−H Alkynylation

S Mondal, T Pinkert, CG Daniliuc… - Angewandte Chemie …, 2021 - Wiley Online Library
Herein, we report a Cp* IrIII‐catalyzed highly regioselective and redox‐neutral protocol for
the construction of 1, 4‐enynes from unactivated olefins and bromoalkynes via …

Recent advances in radical-involved alkynylation of unactivated C (sp3)–H bonds by hydrogen atom abstraction

ZH Zhang, H Wei, ZL Li, XY Liu - Synlett, 2021 - thieme-connect.com
The direct C (sp 3)–H functionalization is one of the major research topics in synthetic
chemistry since C (sp 3)–H bonds are ubiquitous in every aspect of chemistry. Despite …

Synthesis of 1, 4-enynes via nickel-catalyzed cross-coupling of allylic alcohols with alkynylzinc reagents

XY He, ZX Wang - Chemical Communications, 2021 - pubs.rsc.org
Synthesis of 1, 4-enynes was performed via nickel-catalyzed cross-coupling of allylic
alcohols with alkynylzinc reagents. The reaction features high regio-and E/Z-selectivity when …

Photocatalyzed allylic derivatization reactions

P Hünemörder, E Mejía - Catalysis Science & Technology, 2020 - pubs.rsc.org
Catalytic allylation reactions are important methodologies to introduce the versatile allyl
functionality into molecules to produce fine chemicals and synthetic building blocks. Since …