Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration
JV Obligacion, PJ Chirik - Nature Reviews Chemistry, 2018 - nature.com
The addition of X3Si–H or X2B–H (X= H, OR or R) across a C–C multiple bond is a well-
established method for incorporating silane or borane groups, respectively, into …
established method for incorporating silane or borane groups, respectively, into …
Recent advances in catalytic hydrosilylations: developments beyond traditional platinum catalysts
LD de Almeida, H Wang, K Junge… - Angewandte Chemie …, 2021 - Wiley Online Library
Hydrosilylation reactions, which allow the addition of Si− H to C= C/C≡ C bonds, are
typically catalyzed by homogeneous noble metal catalysts (Pt, Rh, Ir, and Ru). Although …
typically catalyzed by homogeneous noble metal catalysts (Pt, Rh, Ir, and Ru). Although …
Recent advances in hydrometallation of alkenes and alkynes via the first row transition metal catalysis
Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl‐or
alkenyl‐metal reagents, which have a wide range of applications in organic transformations …
alkenyl‐metal reagents, which have a wide range of applications in organic transformations …
Walking metals for remote functionalization
H Sommer, F Juliá-Hernández, R Martin… - ACS central …, 2018 - ACS Publications
The distant and selective activation of unreactive C–H and C–C bonds remains one of the
biggest challenges in organic chemistry. In recent years, the development of remote …
biggest challenges in organic chemistry. In recent years, the development of remote …
The recent development of efficient Earth-abundant transition-metal nanocatalysts
D Wang, D Astruc - Chemical Society Reviews, 2017 - pubs.rsc.org
Whereas noble metal compounds have long been central in catalysis, Earth-abundant metal-
based catalysts have in the same time remained undeveloped. Yet the efficacy of Earth …
based catalysts have in the same time remained undeveloped. Yet the efficacy of Earth …
Advances in base-metal-catalyzed alkene hydrosilylation
X Du, Z Huang - ACS Catalysis, 2017 - ACS Publications
This review covers the advance in the development of Fe, Co, and Ni catalysts for the alkene
hydrosilylation reaction, as well as the related dehydrogenative silylation reaction. The …
hydrosilylation reaction, as well as the related dehydrogenative silylation reaction. The …
Nickel‐Catalyzed Electrochemical Reductive Relay Cross‐Coupling of Alkyl Halides to Aryl Halides
KJ Jiao, D Liu, HX Ma, H Qiu, P Fang… - Angewandte …, 2020 - Wiley Online Library
A highly regioselective Ni‐catalyzed electrochemical reductive relay cross‐coupling
between an aryl halide and an alkyl halide has been developed in an undivided cell …
between an aryl halide and an alkyl halide has been developed in an undivided cell …
Nickel-catalyzed multicomponent coupling: synthesis of α-chiral ketones by reductive hydrocarbonylation of alkenes
J Chen, S Zhu - Journal of the American Chemical Society, 2021 - ACS Publications
A nickel-catalyzed, multicomponent regio-and enantioselective coupling via sequential
hydroformylation and carbonylation from readily available starting materials has been …
hydroformylation and carbonylation from readily available starting materials has been …
Mild and regioselective benzylic C–H functionalization: Ni-catalyzed reductive arylation of remote and proximal olefins
Y He, Y Cai, S Zhu - Journal of the American Chemical Society, 2017 - ACS Publications
The synergistic combination of NiH-catalyzed alkene isomerization with nickel-catalyzed
cross-coupling has yielded a general protocol for the synthesis of a wide range of …
cross-coupling has yielded a general protocol for the synthesis of a wide range of …
Nickel-catalyzed cross-electrophile coupling of aryl chlorides with primary alkyl chlorides
S Kim, MJ Goldfogel, MM Gilbert… - Journal of the American …, 2020 - ACS Publications
Alkyl chlorides and aryl chlorides are among the most abundant and stable carbon
electrophiles. Although their coupling with carbon nucleophiles is well developed, the cross …
electrophiles. Although their coupling with carbon nucleophiles is well developed, the cross …