The addition of X3Si–H or X2B–H (X= H, OR or R) across a C–C multiple bond is a well-
established method for incorporating silane or borane groups, respectively, into …

Hydrosilylation reactions, which allow the addition of Si− H to C= C/C≡ C bonds, are
typically catalyzed by homogeneous noble metal catalysts (Pt, Rh, Ir, and Ru). Although …

Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl‐or
alkenyl‐metal reagents, which have a wide range of applications in organic transformations …

The distant and selective activation of unreactive C–H and C–C bonds remains one of the
biggest challenges in organic chemistry. In recent years, the development of remote …

Whereas noble metal compounds have long been central in catalysis, Earth-abundant metal-
based catalysts have in the same time remained undeveloped. Yet the efficacy of Earth …

This review covers the advance in the development of Fe, Co, and Ni catalysts for the alkene
hydrosilylation reaction, as well as the related dehydrogenative silylation reaction. The …

A highly regioselective Ni‐catalyzed electrochemical reductive relay cross‐coupling
between an aryl halide and an alkyl halide has been developed in an undivided cell …

A nickel-catalyzed, multicomponent regio-and enantioselective coupling via sequential
hydroformylation and carbonylation from readily available starting materials has been …

The synergistic combination of NiH-catalyzed alkene isomerization with nickel-catalyzed
cross-coupling has yielded a general protocol for the synthesis of a wide range of …

Alkyl chlorides and aryl chlorides are among the most abundant and stable carbon
electrophiles. Although their coupling with carbon nucleophiles is well developed, the cross …