Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications

Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …

A comprehensive review of recent advances in the synthesis and application of metal-organic frameworks (MOFs) for the adsorptive sequestration of pollutants from …

AN Amenaghawon, CL Anyalewechi… - Separation and …, 2023 - Elsevier
Interest in the use of metal–organic frameworks (MOFs) for the sequestration of pollutants
from aqueous media has been increasing in recent times because of the very desirable …

Insight studies on metal-organic framework nanofibrous membrane adsorption and activation for heavy metal ions removal from aqueous solution

JE Efome, D Rana, T Matsuura… - ACS applied materials & …, 2018 - ACS Publications
Electrospun nanofiber composite membranes containing water-stable metal-organic
frameworks (MOFs) particles (Zr-based MOF-808) supported on polyacrylonitrile (PAN) …

The properties of microwave-assisted synthesis of metal–organic frameworks and their applications

PT Phan, J Hong, N Tran, TH Le - Nanomaterials, 2023 - mdpi.com
Metal–organic frameworks (MOF) are a class of porous materials with various functions
based on their host-guest chemistry. Their selectivity, diffusion kinetics, and catalytic activity …

Functional MOF-based materials for environmental and biomedical applications: A critical review

MA Gatou, IA Vagena, N Lagopati, N Pippa, M Gazouli… - Nanomaterials, 2023 - mdpi.com
Over the last ten years, there has been a growing interest in metal–organic frameworks
(MOFs), which are a unique category of porous materials that combine organic and …

Dynamic weak coordination bonding of chlorocarbons enhances the catalytic performance of a metal–organic framework material

SH Park, RA Peralta, D Moon, NC Jeong - Journal of Materials …, 2022 - pubs.rsc.org
Coordination bondings have shown their critical roles in various inorganic reactions after
Alfred Werner; however, it remains challenging to find extremely weak coordination bonding …

Switchable Metal Sites in Metal–Organic Framework MFM‐300 (Sc): Lewis Acid Catalysis Driven by Metal–Hemilabile Linker Bond Dynamics

RA Peralta, P Lyu, A López‐Olvera… - Angewandte Chemie …, 2022 - Wiley Online Library
Uncommon reversible guest‐induced metal‐hemilabile linker bond dynamics in MOF MFM‐
300 (Sc) was unraveled to switch on/switch off catalytic open metal sites. The catalytic …

Coordinative reduction of metal nodes enhances the hydrolytic stability of a paddlewheel metal–organic framework

D Song, J Bae, H Ji, MB Kim, YS Bae… - Journal of the …, 2019 - ACS Publications
Enhancement of hydrolytic stability of metal–organic frameworks (MOFs) is a challenging
issue in MOF chemistry because most MOFs have shown limitations in their applications …

Catalytic activation of cobalt doping sites in ZIF-71-coated ZnO nanorod arrays for enhancing gas-sensing performance to acetone

T Zhou, S Chen, X Wang, C Xie… - ACS Applied Materials & …, 2020 - ACS Publications
Developing acetone gas sensors with high sensitivity is crucially important for many
applications including nonevasive diagnosis of diabetes. In the present work, cobalt doping …

Drawing sensors with ball-milled blends of metal-organic frameworks and graphite

M Ko, A Aykanat, MK Smith, KA Mirica - Sensors, 2017 - mdpi.com
The synthetically tunable properties and intrinsic porosity of conductive metal-organic
frameworks (MOFs) make them promising materials for transducing selective interactions …