High oxide ion and proton conductivity in a disordered hexagonal perovskite

S Fop, KS McCombie, EJ Wildman, JMS Skakle… - Nature materials, 2020 - nature.com
Oxide ion and proton conductors, which exhibit high conductivity at intermediate
temperature, are necessary to improve the performance of ceramic fuel cells. The crystal …

Solid oxide proton conductors beyond perovskites

S Fop - Journal of Materials Chemistry A, 2021 - pubs.rsc.org
Solid oxide proton conductors are crucially emerging as key materials for enabling hydrogen-
based energy conversion, storage, and electrochemical technologies. Oxides crystallising in …

Remarkably high oxide ion conductivity at low temperature in an ordered fluorite‐type superstructure

X Kuang, JL Payne, MR Johnson… - Angewandte Chemie …, 2012 - Wiley Online Library
Oxide ion conductors are technologically important materials because of their potential
applications in oxygen sensors and pumps, as dense membranes for oxygen permeation …

Oxide Ion Mobility in V- and P-doped Bi2O3-Based Solid Electrolytes: Combining Quasielastic Neutron Scattering with Ab Initio Molecular Dynamics

B Schwaighofer, MA Gonzalez, M Appel… - Chemistry of …, 2023 - ACS Publications
We report the direct observation of oxide ion dynamics on both nano-and picosecond
timescales in the isostructural Bi2O3-derived solid electrolytes Bi0. 852V0. 148O1. 648 and …

Polymorphism and Visible-Light-Driven Photocatalysis of Doped Bi2O3:M (M = S, Se, and Re)

M Weber, RD Rodriguez, DRT Zahn… - Inorganic …, 2022 - ACS Publications
δ-Bi2O3: M (M= S, Se, and Re) with an oxygen-defective fluorite-type structure is obtained
by a coprecipitation method starting from the bismuth oxido cluster [Bi38O45 (OMc) 24 …

Synthesis, Thermodynamic Properties, and Ionic Conductivity of Compounds Based on Bismuth Niobates Doped by Rare-Earth Elements (A Review)

NI Matskevich, AN Semerikova, DA Samoshkin… - Russian Journal of …, 2023 - Springer
Synthesis methods, thermodynamic and functional properties of compounds based on
bismuth niobates doped with rare-earth elements (REEs) are presented. These compounds …

Thermodynamic Characteristics of Bismuth, Gadolinium, Neodymium, and Cobalt Oxide Compounds

NI Matskevich, AN Semerikova, DA Samoshkin… - Russian Journal of …, 2022 - Springer
The standard enthalpies of formation of compounds Bi1. 2Gd0. 8O3 and Bi12. 5Nd1.
5CoO22. 3 were determined by solution calorimetry: Δ f H 0 (Bi1. 2Gd0. 8O3, s, 298.15 K) …

Thermochemical investigation of the new phase Bi12. 5Gd1. 5ReO24. 5

NI Matskevich, AN Bryzgalova, T Wolf… - The Journal of Chemical …, 2012 - Elsevier
The preparation of Bi12. 5Gd1. 5ReO24. 5 has been performed by solid-state reaction from
Bi2O3, Gd2O3, and Re2O7. The phase has been synthesized for the first time. The X-ray …

[HTML][HTML] Variable temperature neutron diffraction study of crystal structure and transport pathways in oxide ion conductors Bi12. 5Ln1. 5ReO24. 5 (Ln= Lu, Er)

CH Hervoches, C Greaves - Solid State Ionics, 2014 - Elsevier
Samples of highly conducting Bi 12.5 Lu 1.5 ReO 24.5 and Bi 12.5 Er 1.5 ReO 24.5 have
been studied by neutron powder diffraction at room temperature for both phases and at 25° …

Bi1− xNbxO1. 5+ x (x= 0.0625, 0.12) fast ion conductors: Structures, stability and oxide ion migration pathways

ML Tate, J Hack, X Kuang, GJ McIntyre… - Journal of Solid State …, 2015 - Elsevier
A combined experimental and computational study of Bi 1− x Nb x O 1.5+ x (x= 0.0625 and
0.12) has been carried out using laboratory X-ray, neutron and electron diffraction …