Theoretical study of nonadiabatic hydrogen atom scattering dynamics on metal surfaces using the hierarchical equations of motion method

X Dan, Q Shi - The Journal of Chemical Physics, 2023 - pubs.aip.org
Hydrogen atom scattering on metal surfaces is investigated based on a simplified Newns–
Anderson model. Both the nuclear and electronic degrees of freedom are treated quantum …

Vibrational energy transfer in collisions of molecules with metal surfaces

I Rahinov, A Kandratsenka, T Schäfer… - Physical Chemistry …, 2024 - pubs.rsc.org
The Born–Oppenheimer approximation (BOA), which serves as the basis for our
understanding of chemical bonding, reactivity and dynamics, is routinely violated for …

Spiers Memorial Lecture: New directions in molecular scattering

GC Schatz, AM Wodtke, X Yang - Faraday Discussions, 2024 - pubs.rsc.org
The field of Molecular Scattering is reviewed as it pertains to gas-gas as well as gas-surface
chemical reaction dynamics. We emphasize the importance of collaboration of experiment …

Room Temperature Hydrogen Atom Scattering Experiments Are Not a Sufficient Benchmark to Validate Electronic Friction Theory

CL Box, N Hertl, WG Stark… - The Journal of Physical …, 2024 - ACS Publications
In the dynamics of atoms and molecules at metal surfaces, electron–hole pair excitations
can play a crucial role. In the case of hyperthermal hydrogen atom scattering, they lead to …

Dissipative friction dynamics within the density-functional based tight-binding scheme

E Michoulier, D Lemoine, F Spiegelman… - The European Physical …, 2023 - Springer
The accurate description of an atom or molecule colliding with a metal surface remains
challenging. Several strategies have been performed over the past decades to include in a …

Inelastic scattering of hydrogen atoms off pristine and hydrogen-covered W (100) surfaces

RM Barrios, O Galparsoro, AM Mesa, LU Piña… - The European Physical …, 2023 - Springer
Recent experiments have shown that translational energy loss is mainly mediated by
electron–hole pair excitations for hydrogen atoms impinging on clean metallic surfaces …

Specular Scattering of H Atoms off Pristine and H-Covered Tungsten Surfaces

R Martin Barrios, N Omar, O Galparsoro… - The Journal of …, 2024 - ACS Publications
Recent theoretical works have evidenced that the presence of hydrogen atoms on tungsten
surfaces increases the probability of incident atoms scattering at specular angles while …

Isotope effects in Eley-Rideal abstraction of Hydrogen from Tungsten surfaces: the role of dissipation.

O Galparsoro, RM Barrios, PEI Almaguer… - Physical Chemistry …, 2024 - pubs.rsc.org
Molecular dynamics simulations are performed to investigate the influence of isotope
substitutions in Eley-Rideal recombination dynamics of hydrogen isotopes from the (100) …