TADF Material Design: Photophysical Background and Case Studies Focusing on Cu(I) and Ag(I) Complexesa

H Yersin, R Czerwieniec, MZ Shafikov… - … : Materials Based on …, 2018 - Wiley Online Library
Designing of thermally activated delayed fluorescence (TADF) compounds with short TADF
decay time and high emission quantum yield is a challenge. This chapter introduces …

Intersystem crossing, phosphorescence, and spin-orbit coupling. Two contrasting Cu (I)-TADF dimers investigated by milli-to micro-second phosphorescence, femto …

H Yersin, R Czerwieniec, U Monkowius… - Coordination Chemistry …, 2023 - Elsevier
Applying femto-second time-resolved spectroscopy, we study intersystem crossing times τ
(ISC) of two Cu (I) dimers, Cu 2 Cl 2 (dppb) 2 1 (dppb= 1, 2-bis-diphenylphosphino) …

Brightly blue and green emitting Cu (I) dimers for singlet harvesting in OLEDs

MJ Leitl, FR Küchle, HA Mayer… - The Journal of …, 2013 - ACS Publications
With the chelating aminophosphane ligands Ph2P-(o-C6H4)-N (CH3) 2 (PNMe2) and Ph2P-
(o-C6H4)-NC4H8 (PNpy), the four halide (Cl, Br, I)-bridged copper coordination compounds …

Cu (I) and Ag (I) complexes with a new type of rigid tridentate N, P, P-ligand for thermally activated delayed fluorescence and OLEDs with high external quantum …

M Klein, N Rau, M Wende, J Sundermeyer… - Chemistry of …, 2020 - ACS Publications
Neutral Cu (I) and Ag (I) complexes with a new rigid tridentate N, P, P ligand (dmpzpp, 3, 5-
dimethyl-1-(2-((2-(di-o-tolyl) phosphanyl)(o-tolyl)-phosphanyl) phenyl)-1 H-pyrazole), giving …

[HTML][HTML] Luminescent Copper (I) complexes as promising materials for the next generation of energy-saving OLED devices

LP Ravaro, KPS Zanoni, ASS de Camargo - Energy Reports, 2020 - Elsevier
The increasing demand for electrical energy by a longer living and increasing population
justifies the search for new, more efficient lighting systems. In this context, organo-metallic …

Thermally activated delayed fluorescence from Ag (I) complexes: a route to 100% quantum yield at unprecedentedly short decay time

MZ Shafikov, AF Suleymanova, R Czerwieniec… - Inorganic …, 2017 - ACS Publications
The four new Ag (I) complexes Ag (phen)(P2-nCB)(1), Ag (idmp)(P2-nCB)(2), Ag (dmp)(P2-
nCB)(3), and Ag (dbp)(P2-nCB)(4) with P2-nCB= bis (diphenylphosphine)-nido-carborane …

Design strategy for Ag (I)-based thermally activated delayed fluorescence reaching an efficiency breakthrough

MZ Shafikov, AF Suleymanova… - Chemistry of …, 2017 - ACS Publications
A design strategy for the development of Ag (I)-based materials for thermally activated
delayed fluorescence (TADF) is presented. Although Ag (I) complexes usually do not show …

Review of organic light-emitting diodes with thermally activated delayed fluorescence emitters for energy-efficient sustainable light sources and displays

D Volz - Journal of photonics for energy, 2016 - spiedigitallibrary.org
Thermally activated delayed fluorescence (TADF) is an emerging hot topic. Even though this
photophysical mechanism itself has been described more than 50 years ago and …

Archetypal iridium (III) compounds for optoelectronic and photonic applications: photophysical properties and synthetic methods

JC Deaton, FN Castellano - Iridium (III) in optoelectronic and …, 2017 - Wiley Online Library
This chapter presents the photophysical properties and synthesis of the archetypal
complexes suitable for the applications of iridium (Ir) complexes. Ir (III) complexes bearing …

Metal–organic and organic TADF-materials: status, challenges and characterization

L Bergmann, DM Zink, S Bräse, T Baumann… - Photoluminescent …, 2017 - Springer
This section covers both metal–organic and organic materials that feature thermally
activated delayed fluorescence (TADF). Such materials are especially useful for organic light …