Conspectus Chain-walking offers extensive opportunities for innovating synthetic methods
that involve constructing chemical bonds at unconventional sites. This approach provides …

The precise construction of chiral molecules is a core research area in chemical science and
technology. Among the plethora of reported synthetic methods, asymmetric catalysis has …

Substantial advances in enantioconvergent C (sp3)–C (sp3) bond formations have been
made with nickel-catalyzed cross-coupling of racemic alkyl electrophiles with organometallic …

The merger of electrochemistry and transition metal catalysis has emerged as a powerful
tool to join two electrophiles in an enantioselective manner. However, the development of …

This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …

Chiral boronic esters are a class of versatile building blocks. We describe herein an
asymmetric nickel-catalyzed borylative coupling of terminal alkenes with nonactivated alkyl …

Metal-catalysed cross-coupling has played a central role in modern chemical synthesis for
decades. Unactivated alkenes, including light olefins, are manufactured on enormous scale …

Transition-metal-catalyzed remote hydrofunctionalization of alkenes remains an efficient but
challenging protocol in chemical synthesis. Herein, we reported a ligand-controlled …

A NiH‐catalyzed migratory hydroalkylation of alkenyl amines with predictable and
switchable regioselectivity is reported. By utilizing a ligand‐controlled, directing group …

Substituted six-membered cyclic hydrocarbons are common constituents of biologically
active compounds. Although methods for the synthesis of thermodynamically favored …