Solution and solid-state structural chemistry of actinide hydrates and their hydrolysis and condensation products

KE Knope, L Soderholm - Chemical Reviews, 2013 - ACS Publications
Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and
Condensation Products | Chemical Reviews ACS ACS Publications C&EN CAS Find my …

Exploring actinide materials through synchrotron radiation techniques

WQ Shi, LY Yuan, CZ Wang, L Wang, L Mei… - Advanced …, 2014 - Wiley Online Library
Synchrotron radiation (SR) based techniques have been utilized with increasing frequency
in the past decade to explore the brilliant and challenging sciences of actinide‐based …

NDTB‐1: A Supertetrahedral Cationic Framework That Removes TcO4 from Solution

S Wang, EV Alekseev, J Diwu, WH Casey… - Angewandte …, 2010 - Wiley Online Library
Materials with charged extended structures are typically based on an anionic network in
which the charge is balanced by cations that fill the space between the anionic portions of …

Selectivity, Kinetics, and Efficiency of Reversible Anion Exchange with TcO4 in a Supertetrahedral Cationic Framework

S Wang, P Yu, BA Purse, MJ Orta… - Advanced Functional …, 2012 - Wiley Online Library
Abstract [ThB5O6 (OH) 6][BO (OH) 2]· 2.5 H2O (Notre Dame Thorium Borate‐1, NDTB‐1) is
an inorganic supertetrahedral cationic framework material that is derived from boric acid flux …

Thorium coordination: A comprehensive review based on coordination number

CD Tutson, AEV Gorden - Coordination Chemistry Reviews, 2017 - Elsevier
Although thorium comprises roughly 8.1 ppm of the Earth, its chemical characteristics and
properties have been relatively underexplored. In large part due to its radioactivity and …

Recent progress in actinide borate chemistry

S Wang, EV Alekseev, W Depmeier… - Chemical …, 2011 - pubs.rsc.org
The use of molten boric acid as a reactive flux for synthesizing actinide borates has been
developed in the past two years providing access to a remarkable array of exotic materials …

Thorium oxo‐clusters as building blocks for open frameworks

C Falaise, K Kozma, M Nyman - Chemistry–A European …, 2018 - Wiley Online Library
Fundamental understanding of tetravalent actinide chemistry is essential to optimize many
steps of the nuclear fuel cycle, as well as to predict actinide speciation in the environment …

Actinyl compounds with hexavalent elements (S, Cr, Se, Mo)–structural diversity, nanoscale chemistry, and cellular automata modeling

SV Krivovichev - European Journal of Inorganic Chemistry, 2010 - Wiley Online Library
Actinyl oxysalts with TO4 tetrahedral oxyanions (T= S, Se, Cr, Mo) demonstrate a remarkable
structural diversity, owing to the flexibility of the An–O–T linkages, which results in a …

Technetium‐99 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4 Ions

P Yu, S Wang, EV Alekseev, W Depmeier… - Angewandte …, 2010 - Wiley Online Library
The generation of energy from nuclear fission results in nonnatural isotopes such as 99Tc.
Like its congener Mn, Tc has a readily accessible+ 7 oxidation state that exists …

Comparisons of plutonium, thorium, and cerium tellurite sulfates

J Lin, JN Cross, J Diwu, NA Meredith… - Inorganic …, 2013 - ACS Publications
The hydrothermal reaction of PuCl3 or CeCl3 with TeO2 in the presence of sulfuric acid
under the comparable conditions results in the crystallization of Pu (TeO3)(SO4) or Ce2 …