Factor analysis applied to the correlation between dissociation constants and solvatochromic parameters in water-acetonitrile mixtures: I. Solvent effects on the …

J Barbosa, G Fonrodona, I Marqués, S Buti… - TrAC Trends in Analytical …, 1997 - Elsevier
The dissociation constants in several acetonitrile-water mixtures of the carboxylic acid
groups of 19 substances, included into four different sets (diuretics, quinolones, buffers and …

Solvent Effects on pKa values of Some Substituted Sulfonamides in Acetonitrile−Water Binary Mixtures by the UV-Spectroscopy Method

S Sanli, Y Altun, N Sanli, G Alsancak… - Journal of chemical & …, 2009 - ACS Publications
The examination of the dissociation constants of sulfonamides is essential in drug-design
studies and in explaining the biopharmaceutical properties of substances. The dissociation …

The application of factor analysis to solvatochromic parameters and pHs values for the standardization of potentiometric sensors in mobile phases used in liquid …

J Barbosa, I Marqués, D Barrón… - TrAC Trends in Analytical …, 1999 - Elsevier
The pHs values for reference buffer solutions in aqueous acetonitrile, methanol, and
tetrahydrofuran mixtures used as mobile phases in LC were subjected to factor analysis in …

Chemometrics

SD Brown, ST Sum, F Despagne… - Analytical Chemistry, 1996 - ACS Publications
Chemometrics is the discipline concerned with the application of statistical and
mathematical methods, as well as those methods based on mathematical logic, to chemistry …

Solvent effects on protonation equilibria of peptides and quinolones by factor analysis applied to the correlation between dissociation constants and solvatochromic …

J Barbosa, G Fonrodona, I Marques, V Sanz-Nebot… - Analytica Chimica …, 1997 - Elsevier
Dissociation constant values of series of peptides and quinolones in 5.54, 10, 16.3, 25 and
50%(w/w) acetonitrile-water mixed solvents at 298.15 K were, firstly, submitted to factor …

Study of solvent composition effects on the protonation equilibria of various anilines by multiple linear regression and factor analysis applied to the correlation …

Y Altun - Journal of solution chemistry, 2004 - Springer
The stoichiometric protonation constants (logβ) of aniline derivatives were determined
potentiometrically over a wide range of solvent composition (0–0.74 mole fraction of …

Characterization and prediction of solute properties in methanol–water association by chemometrics analysis of solvation data

B Hemmateenejad - Journal of Chemometrics: A Journal of the …, 2005 - Wiley Online Library
Methanol–water binary mixtures have been characterized as a ternary or quaternary system
composed of unassociated methanol (M) and water (W) and one or two methanol–water …

Solvent effects on mobile phases used in liquid chromatography: factor analysis applied to protonation equilibria and solvatochromic parameters

I Marques, G Fonrodona, S Butı́, J Barbosa - TrAC Trends in Analytical …, 1999 - Elsevier
Dissociation constant values of the acid components of the standard NIST scale buffer
solutions and of acetate buffer in several hydroorganic mixtures (acetonitrile–water …

Understanding the role of noncovalent interactions on the rate of some Diels‐Alder reactions in different solvents

A Mehranfar, M Izadyar, M Khavani… - … Journal of Quantum …, 2019 - Wiley Online Library
In this article, the role of noncovalent interactions (NCI) on four types of cycloaddition
reactions in different solvents was investigated by employing quantum chemistry …

The importance of polarity/polarizability interaction on the acidity behavior of 9, 10-anthraquinone and 9-anthrone derivatives in methanol-water mixed solvents using …

B Hemmateenejad, H Sharghi, M Akhond… - Journal of solution …, 2003 - Springer
The influence of solvent properties on acidity constants of some newly synthesized 9, 10-
anthraquinone and 9-anthrone derivatives was studied in methanol-water mixtures in a …