The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

Dearomatization strategies in a multicomponent fashion often result in complex heterocyclic
frameworks, which have attracted the attention of chemists due to their natural product-like …

Dearomative photocycloaddition of monocyclic arenes is an appealing strategy for
comprehending the concept of “escape from flatland”. This brings the replacement of readily …

Asymmetric organocatalytic oxidations have been witnessed to an impressive development
in the last years thanks to the establishment of important chiral hypervalent iodines (III/V) …

Starting from the early 1990s, the chemistry of polyvalent iodine organic compounds has
experienced an explosive development. This surging interest in iodine compounds is mainly …

A Rh-catalyzed enantioselective dearomatization of 1-aryl-2-naphthols with internal alkynes
via C–H functionalization reaction was achieved. In the presence of a chiral Cp/Rh catalyst …

Electrophilic aromatic substitution is among the most widely used mechanistic manifolds in
organic chemistry. Access to certain substitution patterns is, however, precluded by intrinsic …

The iodines (III) have it: The rational design of a conformationally flexible C 2‐symmetric
iodosylarene catalyst has been used for the enantioselective Kita oxidative …

In this work, a dual-size MOF-derived Co catalyst (0.2 Co 1-NPs@ NC) composed of single
atoms (Co 1) and highly dispersed nanoparticles (Co NPs) was prepared by in-situ Zn …

This report details the development of a spirobiindane-based chiral hypervalent iodine
reagent, especially focusing on its structural elucidation for effective asymmetric induction of …