Thermal stability of ionic liquids: Current status and prospects for future development
C Xu, Z Cheng - Processes, 2021 - mdpi.com
Ionic liquids (ILs) are the safest solvent in various high-temperature applications due to their
non-flammable properties. In order to obtain their thermal stability properties …
non-flammable properties. In order to obtain their thermal stability properties …
Recent advancements in the ionic liquid mediated lignin valorization for the production of renewable materials and value-added chemicals
Lignin is the most abundant aromatic polymer available on earth and is a recalcitrant by-
product in the lignocellulose biomass-based industry. In recent times even though about 1 g …
product in the lignocellulose biomass-based industry. In recent times even though about 1 g …
Tuning the melting point of selected ionic liquids through adjustment of the cation's dipole moment
BD Rabideau, M Soltani, RA Parker, B Siu… - Physical Chemistry …, 2020 - pubs.rsc.org
In previous work with thermally robust salts [Cassity et al., Phys. Chem. Chem. Phys., 2017,
19, 31560] it was noted that an increase in the dipole moment of the cation generally led to a …
19, 31560] it was noted that an increase in the dipole moment of the cation generally led to a …
Thermally-stable imidazolium dicationic ionic liquids with pyridine functional groups
CJ Clarke, L Bui-Le, JP Hallett… - … Sustainable Chemistry & …, 2020 - ACS Publications
Thermally-stable ionic liquids (ILs) have limited structural possibilities and lack coordinating
anions or functional groups. Thermal stability effectively incurs a tunability penalty, limiting …
anions or functional groups. Thermal stability effectively incurs a tunability penalty, limiting …
Making good on a promise: ionic liquids with genuinely high degrees of thermal stability
Thermally robust materials have been of interest since the middle of the past century for use
as high temperature structural materials, lubricants, heat transfer fluids and other uses …
as high temperature structural materials, lubricants, heat transfer fluids and other uses …
Synthesis, structures, DFT calculations, and Hirshfeld surface analysis of sulfonium derivatives of the closo-decaborate anion [B10X9-cyclo-S (CH2) 4]–and [B10X9 …
AS Kubasov, AV Golubev, AY Bykov… - Journal of Molecular …, 2021 - Elsevier
This work is devoted to the synthesis and modification of sulfur-containing derivatives of the
closo-decaborate anion with cyclic substituents [2–B 10 H 9–cyclo–S (CH 2) 4]–(1) and [2–B …
closo-decaborate anion with cyclic substituents [2–B 10 H 9–cyclo–S (CH 2) 4]–(1) and [2–B …
Thermal stability of choline based amino acid ionic liquids
S Bhattacharyya, FU Shah - Journal of Molecular Liquids, 2018 - Elsevier
Thermal stability of different choline based amino acid ionic liquids were studied. Both short
term as well as long term thermal studies were carried out. Long term thermal studies of all …
term as well as long term thermal studies were carried out. Long term thermal studies of all …
Ultra-high thermal stability perarylated ionic liquids as gas chromatographic stationary phases for the selective separation of polyaromatic hydrocarbons and …
Ionic liquids (ILs) are well-known in the field of separation science for their unique selectivity
when used as stationary phases in gas chromatography (GC). While a significant amount of …
when used as stationary phases in gas chromatography (GC). While a significant amount of …
The effect of structural modifications on the thermal stability, melting points and ion interactions for a series of tetraaryl-phosphonium-based mesothermal ionic liquids
CA Cassity, B Siu, M Soltani, JL McGeehee… - Physical Chemistry …, 2017 - pubs.rsc.org
A family of mesothermal ionic liquids comprised of tetraarylphosphonium cations and the bis
(trifluoromethanesulfonyl) amidate anion are shown to be materials of exceptional thermal …
(trifluoromethanesulfonyl) amidate anion are shown to be materials of exceptional thermal …
Developing Structural First Principles for Alkylated Triphenylphosphonium-Based Ionic Liquids
B O'Rourke, C Lauderback, LI Teodoro, M Grimm… - ACS …, 2021 - ACS Publications
While ionic liquids have proved to be versatile materials for a wide spectrum of applications,
eg, energy, materials, and medicine, several challenges remain concerning the rational …
eg, energy, materials, and medicine, several challenges remain concerning the rational …