[HTML][HTML] Artificial molecular machines

S Erbas-Cakmak, DA Leigh, CT McTernan… - Chemical …, 2015 - ACS Publications
The widespread use of molecular machines in biology has long suggested that great
rewards could come from bridging the gap between synthetic molecular systems and the …

Development of pseudorotaxanes and rotaxanes: from synthesis to stimuli-responsive motions to applications

M Xue, Y Yang, X Chi, X Yan, F Huang - Chemical reviews, 2015 - ACS Publications
The history of isomeric types of organic molecules has passed through several important
stages:(1) Molecules that differ from each other with different numbers and types of atoms;(2) …

Active template strategy for the preparation of π-conjugated interlocked nanocarbons

JH May, JM Van Raden, RL Maust, LN Zakharov… - Nature Chemistry, 2023 - nature.com
Mechanically interlocked carbon nanostructures represent a relatively unexplored frontier in
carbon nanoscience due to the difficulty in preparing these unusual topological materials …

The active template approach to interlocked molecules

M Denis, SM Goldup - Nature Reviews Chemistry, 2017 - nature.com
The active template approach to interlocked molecules takes advantage of the ability of
metal ions to both organize precursor fragments for mechanical bond formation and to …

(Nano) mechanical motion triggered by metal coordination: from functional devices to networked multicomponent catalytic machinery

A Goswami, S Saha, PK Biswas, M Schmittel - Chemical reviews, 2019 - ACS Publications
A look at the elegance and efficiency of biological machines readily reveals that Nature
masters the full gamut of chemical interactions to compose masterpieces of the living world …

Polymeric rotaxanes

A Harada, A Hashidzume, H Yamaguchi… - Chemical …, 2009 - ACS Publications
In the past three decades, chemistry has changed from focusing on a single molecule to
molecular assemblies. Through the discovery of macrocycles, the chemistry of molecular …

Active metal template synthesis of rotaxanes, catenanes and molecular shuttles

JD Crowley, SM Goldup, AL Lee, DA Leigh… - Chemical Society …, 2009 - pubs.rsc.org
Active metal template synthesis is a powerful new strategy for the construction of rotaxanes,
catenanes and other mechanically interlocked molecular structures. The key feature is that …

Metal ions in the synthesis of interlocked molecules and materials

JEM Lewis, PD Beer, SJ Loeb… - Chemical Society Reviews, 2017 - pubs.rsc.org
The use of metal ions to template the synthesis of catenanes by Sauvage and co-workers
was a pivotal moment in the development of the field of interlocked molecules. In this …

Rotaxane catalysts

DA Leigh, V Marcos, MR Wilson - Acs Catalysis, 2014 - ACS Publications
Rotaxanes are molecules composed of one or more macrocycles threaded onto one or more
axles that bear bulky stoppers to prevent the macrocycles from slipping off. 1 The first …

Exploiting the mechanical bond effect for enhanced molecular recognition and sensing

JT Wilmore, PD Beer - Advanced Materials, 2024 - Wiley Online Library
The ubiquity of charged species in biological and industrial processes has resulted in ever‐
increasing interest in their selective recognition, detection, and environmental remediation …