Synthetic photoelectrochemistry (PEC) is receiving increasing attention as a new frontier for
the generation and handling of reactive intermediates. PEC permits selective single …

In the last decade, photoredox catalysis has unlocked unprecedented reactivities in
synthetic organic chemistry. Seminal advancements in the field have involved the use of well …

High value utilization of carbon dioxide (CO2) has attracted worldwide attention for decades.
Catalytic carboxylation of alkenes with CO2 to synthesize valuable carboxylic acids and …

Since the seminal work of Zhang in 2016, donor–acceptor cyanoarene-based fluorophores,
such as 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN), have been widely …

General photoactivation of electron donor–acceptor (EDA) complexes between
arylsulfonium salts and 1, 4-diazabicyclo [2.2. 2] octane with visible light or natural sunlight …

Cyanoarene-based photocatalysts (PCs) have attracted significant interest owing to their
superior catalytic performance for radical anion mediated photoredox catalysis. However …

Thiol is known to act as a hydrogen atom transfer catalyst working in synergy with a
photocatalyst in photoredox catalysis, but we report herein that an arene thiolate with an …

Herein we disclose a strategy to promote the hydrocarboxylation of unactivated alkenes
using photochemical activation of formate salts. We illustrate that an alternative initiation …

Herein, an electroreductive carboxylation of organic carbon‐halogen bonds (X= Br and Cl)
promoted by catalytic amounts of naphthalene as an organic mediator is reported. This …

The generation of carbon radicals by halogen-atom and group transfer reactions is generally
achieved using tin and silicon reagents that maximize the interplay of enthalpic …