Fluorinated metal–organic frameworks for gas separation

AE Amooghin, H Sanaeepur, R Luque… - Chemical Society …, 2022 - pubs.rsc.org
Fluorinated metal–organic frameworks (F-MOFs) as fast-growing porous materials have
revolutionized the field of gas separation due to their tunable pore apertures, appealing …

Progress and potential of metal-organic frameworks (MOFs) for gas storage and separation: A review

T Jia, Y Gu, F Li - Journal of Environmental Chemical Engineering, 2022 - Elsevier
Gas storage and separation plays the most critically vital role in the utilization of energy
resources and the petrochemical industry in modern society. The development of industry …

Benchmark single-step ethylene purification from ternary mixtures by a customized fluorinated anion-embedded MOF

Y Jiang, Y Hu, B Luan, L Wang, R Krishna, H Ni… - Nature …, 2023 - nature.com
Abstract Ethylene (C2H4) purification from multi-component mixtures by physical adsorption
is a great challenge in the chemical industry. Herein, we report a GeF62-anion embedded …

Pore modulation of hydrogen‐bonded organic frameworks for efficient separation of propylene

Y Cai, J Gao, JH Li, P Liu, Y Zheng, W Zhou… - Angewandte …, 2023 - Wiley Online Library
Developing hydrogen‐bonded organic frameworks (HOFs) that combine functional sites,
size control, and storage capability for targeting gas molecule capture is a novel and …

Orthogonal-array dynamic molecular sieving of propylene/propane mixtures

H Zeng, M Xie, T Wang, RJ Wei, XJ Xie, Y Zhao, W Lu… - Nature, 2021 - nature.com
Rigid molecular sieving materials work well for small molecules with the complete exclusion
of large ones,–, and molecules with matching physiochemical properties may be separated …

Metal–organic framework based hydrogen-bonding nanotrap for efficient acetylene storage and separation

Y Ye, S Xian, H Cui, K Tan, L Gong… - Journal of the …, 2021 - ACS Publications
The removal of carbon dioxide (CO2) from acetylene (C2H2) is a critical industrial process
for manufacturing high-purity C2H2. However, it remains challenging to address the tradeoff …

Immobilization of lewis basic sites into a stable ethane-selective MOF enabling one-step separation of ethylene from a ternary mixture

XW Gu, JX Wang, E Wu, H Wu, W Zhou… - Journal of the …, 2022 - ACS Publications
Purification of C2H4 from a ternary C2H2/C2H6/C2H4 mixture by one-step adsorption
separation is of prime importance but challenging in the petrochemical industry; however …

A microporous 2D cobalt-based MOF with pyridyl sites and open metal sites for selective adsorption of CO2

L Qin, Y Li, F Liang, L Li, Y Lan, Z Li, X Lu… - Microporous and …, 2022 - Elsevier
A new microporous 2D Co-based MOF,[Co 3 (C 6 H 3 NO 2) 2 (cpna) 2 (DMA) 2] n (1)(H 2
cpna= 6-(4-carboxylphenyl) nicotinic acid; DMA= N, N-dimethylacetamide), has been …

Achieving high performance metal–organic framework materials through pore engineering

RB Lin, Z Zhang, B Chen - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Achieving high performance functional materials has been a long-term goal for
scientists and engineers that can significantly promote science and technology development …

Topological design of unprecedented metal‐organic frameworks featuring multiple anion functionalities and hierarchical porosity for benchmark acetylene separation

Y Zhang, W Sun, B Luan, J Li, D Luo… - Angewandte Chemie …, 2023 - Wiley Online Library
Separation of acetylene (C2H2) from carbon dioxide (CO2) or ethylene (C2H4) is industrially
important but still challenging so far. Herein, we developed two novel robust metal organic …