Geometric and electronic structure/function correlations in non-heme iron enzymes
EI Solomon, TC Brunold, MI Davis, JN Kemsley… - Chemical …, 2000 - ACS Publications
In recent years, significant progress has been made in understanding the geometric and
electronic structures of the active sites of non-heme iron enzymes and the contributions of …
electronic structures of the active sites of non-heme iron enzymes and the contributions of …
A mononuclear Fe (III) single molecule magnet with a 3/2↔ 5/2 spin crossover
The air stable complex [(PNP) FeCl2](1)(PNP= N [2-P (CHMe2) 2-4-methylphenyl] 2–),
prepared from one-electron oxidation of [(PNP) FeCl] with ClCPh3, displays an unexpected …
prepared from one-electron oxidation of [(PNP) FeCl] with ClCPh3, displays an unexpected …
Axial ligation modes in iron (III) Porphyrins. Models for the oxidized reaction states of cytochrome P-450 enzymes and the molecular structure of iron (III) …
SC Tang, S Koch, GC Papaefthymiou… - Journal of the …, 1976 - ACS Publications
Cytochrome P-450 monooxygenaseenzymes contain a protoporphyrin IX prosthetic
groupand exhibit five reac-tion states, in each of whichthe nature of axial ligation to Fe (II, III) …
groupand exhibit five reac-tion states, in each of whichthe nature of axial ligation to Fe (II, III) …
Iron (II, III)-chlorin and-isobacteriochlorin complexes. Models of the heme prosthetic groups in nitrite and sulfite reductases: means of formation and spectroscopic and …
AM Stolzenberg, SH Strauss… - Journal of the American …, 1981 - ACS Publications
Abstract; Extensive series of iron (II, III)-hydroporphyrin complexes of the types Fe (P) L,[Fe
(P) LL'] 0,+,[Fe (P)] 20, and Fe (P), with P= octaethylchlorin (OEC) and …
(P) LL'] 0,+,[Fe (P)] 20, and Fe (P), with P= octaethylchlorin (OEC) and …
The Electronic Structures of an Isostructural Series of Octahedral Nitrosyliron Complexes {Fe−NO}6,7,8 Elucidated by Mössbauer Spectroscopy
C Hauser, T Glaser, E Bill, T Weyhermüller… - Journal of the …, 2000 - ACS Publications
From the reaction of cis-[(cyclam) FeIII (Cl) 2] Cl (cyclam= 1, 4, 8, 11-
tetraazacyclotetradecane) with hydroxylamine in water the octahedral nitrosyliron …
tetraazacyclotetradecane) with hydroxylamine in water the octahedral nitrosyliron …
Inorganic derivatives of iron sulfide thiolate dimers and tetramers: Synthesis and properties of the halide series [Fe2S2X4] 2-and [Fe4S4X4] 2-(X= chlorine, bromine …
GB Wong, MA Bobrik, RH Holm - Inorganic Chemistry, 1978 - ACS Publications
Introduction The binuclear and tetranuclear iron sulfide thiolate com-plexes of the general
types [Fe2S2 (SR) 4] 2-and [Fe4S4 (SR) 4] 2-, respectively, have enjoyed substantial utility …
types [Fe2S2 (SR) 4] 2-and [Fe4S4 (SR) 4] 2-, respectively, have enjoyed substantial utility …
Tuning the Electronic Structure of Halidobis(o‐imino‐benzosemiquinonato)iron(III) Complexes
H Chun, T Weyhermüller, E Bill… - Angewandte Chemie …, 2001 - Wiley Online Library
Mononuclear complexes of iron (iii)(d5) containing redoxinert, closed-shell (™ innocent∫)
ligands adopt either a high-, intermediate-, or low-spin electron configuration: SFe à 5 2, 3 2 …
ligands adopt either a high-, intermediate-, or low-spin electron configuration: SFe à 5 2, 3 2 …
Intermediate-spin (S= 3/2) porphyrinatoiron (III) complexes
DH Dolphin, JR Sams, TB Tsin - Inorganic Chemistry, 1977 - ACS Publications
There is much current interest in the synthesis of new iron porphyrin complexes having
unusual electronic states or co-ordinations. The most common types of iron porphyrins are …
unusual electronic states or co-ordinations. The most common types of iron porphyrins are …
Synthesis and structural systematics of ethane-1, 2-dithiolato complexes
CP Rao, JR Dorfman, RH Holm - Inorganic chemistry, 1986 - ACS Publications
Evolvement of the metal complex chemistry of thiolates, a fundamental ligand type, has
proceeded so rapidly, particularly over the last half-dozen years, that our knowledge of …
proceeded so rapidly, particularly over the last half-dozen years, that our knowledge of …
S = 3/2 ⇋ S = 1/2 Spin Crossover Behavior in Five-Coordinate Halido- and Pseudohalido-bis(o-iminobenzosemiquinonato)iron(III) Complexes
H Chun, E Bill, T Weyhermüller, K Wieghardt - Inorganic chemistry, 2003 - ACS Publications
Five-coordinate halido-and pseudohalido-bis (o-iminobenzosemiquinonato) iron (III)
complexes [FeIIIX (LISQ) 2](X= Cl-(1), Br-(2a, 2b), I-(3), N3-(4), and NCS-(5)) have been …
complexes [FeIIIX (LISQ) 2](X= Cl-(1), Br-(2a, 2b), I-(3), N3-(4), and NCS-(5)) have been …