Chiral metal–organic frameworks
In the past two decades, metal–organic frameworks (MOFs) or porous coordination polymers
(PCPs) assembled from metal ions or clusters and organic linkers via metal–ligand …
(PCPs) assembled from metal ions or clusters and organic linkers via metal–ligand …
Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers
P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
Chiral supramolecular polymers
As an active branch within the field of supramolecular polymers, chiral supramolecular
polymers (SPs) are an excellent benchmark to generate helical structures that can clarify the …
polymers (SPs) are an excellent benchmark to generate helical structures that can clarify the …
Possible chemical and physical scenarios towards biological homochirality
Q Sallembien, L Bouteiller, J Crassous… - Chemical Society …, 2022 - pubs.rsc.org
The single chirality of biological molecules in terrestrial biology raises more questions than
certitudes about its origin. The emergence of biological homochirality (BH) and its …
certitudes about its origin. The emergence of biological homochirality (BH) and its …
Light-empowered contra-thermodynamic stereochemical editing
PZ Wang, WJ Xiao, JR Chen - Nature Reviews Chemistry, 2023 - nature.com
Creating, conserving and modifying the stereochemistry of organic compounds has been the
subject of significant research efforts in synthetic chemistry. Most synthetic routes are …
subject of significant research efforts in synthetic chemistry. Most synthetic routes are …
Vibrational circular dichroism spectroscopy of chiral molecular crystals: insights from theory
S Jähnigen - Angewandte Chemie International Edition, 2023 - Wiley Online Library
Chirality is a curious phenomenon that appears in various forms. While the concept of
molecular (RS‐) chirality is ubiquitous in chemistry, there are also more intricate forms of …
molecular (RS‐) chirality is ubiquitous in chemistry, there are also more intricate forms of …
Chiral Molecular Cage with Tunable Stereoinversion Barriers
WB Gao, Z Li, T Tong, X Dong, H Qu… - Journal of the …, 2023 - ACS Publications
The manipulation of chirality in molecular entities that rapidly interconvert between
enantiomeric forms is challenging, particularly at the supramolecular level. Advances in …
enantiomeric forms is challenging, particularly at the supramolecular level. Advances in …
Catalytic deracemization reactions
M Huang, T Pan, X Jiang, S Luo - Journal of the American …, 2023 - ACS Publications
Deracemization, which converts a racemate into its single enantiomer without separation of
the intermediate, has gained renewed interest in asymmetric synthesis with its inherent …
the intermediate, has gained renewed interest in asymmetric synthesis with its inherent …
Chiral stationary phases and applications in gas chromatography
G Betzenbichler, L Huber, S Kräh, MLK Morkos… - Chirality, 2022 - Wiley Online Library
Chiral compounds are ubiquitous in nature and play a pivotal role in biochemical processes,
in chiroptical materials and applications, and as chiral drugs. The analysis and …
in chiroptical materials and applications, and as chiral drugs. The analysis and …
Strategies for chiral separation: from racemate to enantiomer
J Sui, N Wang, J Wang, X Huang, T Wang, L Zhou… - Chemical …, 2023 - pubs.rsc.org
Chiral separation has already become a crucial topic for effectively utilizing superfluous
racemates synthesized by chemical means and satisfying the growing requirements for …
racemates synthesized by chemical means and satisfying the growing requirements for …