Chiral metal–organic frameworks

W Gong, Z Chen, J Dong, Y Liu, Y Cui - Chemical Reviews, 2022 - ACS Publications
In the past two decades, metal–organic frameworks (MOFs) or porous coordination polymers
(PCPs) assembled from metal ions or clusters and organic linkers via metal–ligand …

Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers

P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Chiral supramolecular polymers

F García, R Gómez, L Sánchez - Chemical Society Reviews, 2023 - pubs.rsc.org
As an active branch within the field of supramolecular polymers, chiral supramolecular
polymers (SPs) are an excellent benchmark to generate helical structures that can clarify the …

Possible chemical and physical scenarios towards biological homochirality

Q Sallembien, L Bouteiller, J Crassous… - Chemical Society …, 2022 - pubs.rsc.org
The single chirality of biological molecules in terrestrial biology raises more questions than
certitudes about its origin. The emergence of biological homochirality (BH) and its …

Light-empowered contra-thermodynamic stereochemical editing

PZ Wang, WJ Xiao, JR Chen - Nature Reviews Chemistry, 2023 - nature.com
Creating, conserving and modifying the stereochemistry of organic compounds has been the
subject of significant research efforts in synthetic chemistry. Most synthetic routes are …

Vibrational circular dichroism spectroscopy of chiral molecular crystals: insights from theory

S Jähnigen - Angewandte Chemie International Edition, 2023 - Wiley Online Library
Chirality is a curious phenomenon that appears in various forms. While the concept of
molecular (RS‐) chirality is ubiquitous in chemistry, there are also more intricate forms of …

Chiral Molecular Cage with Tunable Stereoinversion Barriers

WB Gao, Z Li, T Tong, X Dong, H Qu… - Journal of the …, 2023 - ACS Publications
The manipulation of chirality in molecular entities that rapidly interconvert between
enantiomeric forms is challenging, particularly at the supramolecular level. Advances in …

Catalytic deracemization reactions

M Huang, T Pan, X Jiang, S Luo - Journal of the American …, 2023 - ACS Publications
Deracemization, which converts a racemate into its single enantiomer without separation of
the intermediate, has gained renewed interest in asymmetric synthesis with its inherent …

Chiral stationary phases and applications in gas chromatography

G Betzenbichler, L Huber, S Kräh, MLK Morkos… - Chirality, 2022 - Wiley Online Library
Chiral compounds are ubiquitous in nature and play a pivotal role in biochemical processes,
in chiroptical materials and applications, and as chiral drugs. The analysis and …

Strategies for chiral separation: from racemate to enantiomer

J Sui, N Wang, J Wang, X Huang, T Wang, L Zhou… - Chemical …, 2023 - pubs.rsc.org
Chiral separation has already become a crucial topic for effectively utilizing superfluous
racemates synthesized by chemical means and satisfying the growing requirements for …