[HTML][HTML] Metal-catalysed C–H bond activation and borylation

R Bisht, C Haldar, MMM Hassan, ME Hoque… - Chemical Society …, 2022 - pubs.rsc.org
Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

First-row d-block element-catalyzed carbon–boron bond formation and related processes

SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

[HTML][HTML] Recent advances in asymmetric borylation by transition metal catalysis

J Hu, M Ferger, Z Shi, TB Marder - Chemical Society Reviews, 2021 - pubs.rsc.org
Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …

Photoinduced borylation for the synthesis of organoboron compounds: focus review

YM Tian, XN Guo, H Braunschweig, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …

Redox reactions of small organic molecules using ball milling and piezoelectric materials

K Kubota, Y Pang, A Miura, H Ito - Science, 2019 - science.org
Over the past decade, photoredox catalysis has harnessed light energy to accelerate bond-
forming reactions. We postulated that a complementary method for the redox-activation of …

Unveiling extreme photoreduction potentials of donor–acceptor cyanoarenes to access aryl radicals from aryl chlorides

J Xu, J Cao, X Wu, H Wang, X Yang… - Journal of the …, 2021 - ACS Publications
Since the seminal work of Zhang in 2016, donor–acceptor cyanoarene-based fluorophores,
such as 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN), have been widely …

Diboron (4) compounds: from structural curiosity to synthetic workhorse

EC Neeve, SJ Geier, IAI Mkhalid, SA Westcott… - Chemical …, 2016 - ACS Publications
Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Photoinduced decarboxylative borylation of carboxylic acids

A Fawcett, J Pradeilles, Y Wang, T Mutsuga, EL Myers… - Science, 2017 - science.org
The conversion of widely available carboxylic acids into versatile boronic esters would be
highly enabling for synthesis. We found that this transformation can be effected by …

Decarboxylative borylation and cross-coupling of (hetero) aryl acids enabled by copper charge transfer catalysis

NW Dow, PS Pedersen, TQ Chen… - Journal of the …, 2022 - ACS Publications
We report a copper-catalyzed strategy for arylboronic ester synthesis that exploits
photoinduced ligand-to-metal charge transfer (LMCT) to convert (hetero) aryl acids into aryl …

Copper-boryl mediated organic synthesis

D Hemming, R Fritzemeier, SA Westcott… - Chemical Society …, 2018 - pubs.rsc.org
Organoboron compounds are valuable synthetic intermediates that find application in a
diverse variety of processes including both C–X and C–C bond-forming transformations …