[HTML][HTML] Metal-catalysed C–H bond activation and borylation
Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …
received a remarkable level of attention as a popular reaction in the synthesis of …
First-row d-block element-catalyzed carbon–boron bond formation and related processes
SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
[HTML][HTML] Recent advances in asymmetric borylation by transition metal catalysis
J Hu, M Ferger, Z Shi, TB Marder - Chemical Society Reviews, 2021 - pubs.rsc.org
Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …
development of materials science and pharmaceuticals. Much effort has been devoted to …
Photoinduced borylation for the synthesis of organoboron compounds: focus review
YM Tian, XN Guo, H Braunschweig, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …
transformations. The development of practical and convenient ways to synthesize boronate …
Redox reactions of small organic molecules using ball milling and piezoelectric materials
Over the past decade, photoredox catalysis has harnessed light energy to accelerate bond-
forming reactions. We postulated that a complementary method for the redox-activation of …
forming reactions. We postulated that a complementary method for the redox-activation of …
Unveiling extreme photoreduction potentials of donor–acceptor cyanoarenes to access aryl radicals from aryl chlorides
Since the seminal work of Zhang in 2016, donor–acceptor cyanoarene-based fluorophores,
such as 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN), have been widely …
such as 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN), have been widely …
Diboron (4) compounds: from structural curiosity to synthetic workhorse
Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …
(4) compounds been extensively explored. Many interesting structural features and reaction …
Photoinduced decarboxylative borylation of carboxylic acids
A Fawcett, J Pradeilles, Y Wang, T Mutsuga, EL Myers… - Science, 2017 - science.org
The conversion of widely available carboxylic acids into versatile boronic esters would be
highly enabling for synthesis. We found that this transformation can be effected by …
highly enabling for synthesis. We found that this transformation can be effected by …
Decarboxylative borylation and cross-coupling of (hetero) aryl acids enabled by copper charge transfer catalysis
NW Dow, PS Pedersen, TQ Chen… - Journal of the …, 2022 - ACS Publications
We report a copper-catalyzed strategy for arylboronic ester synthesis that exploits
photoinduced ligand-to-metal charge transfer (LMCT) to convert (hetero) aryl acids into aryl …
photoinduced ligand-to-metal charge transfer (LMCT) to convert (hetero) aryl acids into aryl …
Copper-boryl mediated organic synthesis
D Hemming, R Fritzemeier, SA Westcott… - Chemical Society …, 2018 - pubs.rsc.org
Organoboron compounds are valuable synthetic intermediates that find application in a
diverse variety of processes including both C–X and C–C bond-forming transformations …
diverse variety of processes including both C–X and C–C bond-forming transformations …