Nature of the states in actinide metals

KT Moore, G van der Laan - Reviews of Modern Physics, 2009 - APS
Actinide elements produce a plethora of interesting physical behaviors due to the 5 f states.
This review compiles and analyzes progress in the understanding of the electronic and …

[HTML][HTML] Discovery and design of nuclear fuels

M Stan - Materials Today, 2009 - Elsevier
To facilitate the discovery and design of innovative nuclear fuels, multi-scale models and
simulations are used to predict irradiation effects on properties such as thermal conductivity …

Multiconfigurational nature of 5f orbitals in uranium and plutonium intermetallics

CH Booth, Y Jiang, DL Wang… - Proceedings of the …, 2012 - National Acad Sciences
Uranium and plutonium's 5f electrons are tenuously poised between strongly bonding with
ligand spd-states and residing close to the nucleus. The unusual properties of these …

Transuranium Sulfide via the Boron Chalcogen Mixture Method and Reversible Water Uptake in the NaCuTS3 Family

AA Berseneva, VV Klepov, K Pal, K Seeley… - Journal of the …, 2022 - ACS Publications
The behavior of 5f electrons in soft ligand environments makes actinides, and especially
transuranium chalcogenides, an intriguing class of materials for fundamental studies. Due to …

Nature of the electronic structure of plutonium

L Huang, H Lu - Physical Review B, 2020 - APS
Plutonium (Pu), in which the 5 f valence electrons always wander the boundary between
localized and itinerant states, exhibits quite complex crystal structures and unprecedentedly …

Advances in actinide thin films: synthesis, properties, and future directions

KD Vallejo, F Kabir, N Poudel… - Reports on Progress …, 2022 - iopscience.iop.org
Actinide-based compounds exhibit unique physics due to the presence of 5f electrons, and
serve in many cases as important technological materials. Targeted thin film synthesis of …

[HTML][HTML] Superconductivity in transuranium elements and compounds

JC Griveau, É Colineau - Comptes Rendus Physique, 2014 - Elsevier
We present here an overview of the properties of transuranium superconductors, but also of
the (non-superconducting) transuranium analogues of uranium superconductors. We briefly …

Pressure-driven localized-itinerant transition and valence fluctuation in cubic phase californium

L Huang, H Lu - Physical Review B, 2019 - APS
A combination of the density functional theory and the single-site dynamical mean-field
theory is employed to study the pressure dependence of the electronic structure for cubic …

Temperature-driven itinerant–localized crossover in the heavy-fermion compound

H Lu, L Huang - Physical Review B, 2021 - APS
The temperature-dependent evolution pattern of 5 f electrons helps to elucidate the long-
standing itinerant-localized dual nature in plutonium-based compounds. In this work, we …

Nanoscale heterogeneity, premartensitic nucleation, and a new plutonium structure in metastable δ fcc Pu-Ga alloys

SD Conradson, N Bock, JM Castro, DR Conradson… - Physical Review B, 2014 - APS
The scientifically fascinating question of the spatial extent and bonding of the 5 f orbitals of
Pu and its six different phases extends to its δ-retained alloys and the mechanism by which …