Exciton Diffusion and Annihilation in an sp2 Carbon-Conjugated Covalent Organic Framework

X Zhang, K Geng, D Jiang… - Journal of the American …, 2022 - ACS Publications
To optimize the optical and optoelectronic functionalities of two-dimensional (2D) covalent
organic frameworks (COFs), detailed properties of emissive and nonradiative pathways after …

Toward high‐performance dihydrophenazine‐based conjugated microporous polymer cathodes for dual‐ion batteries through donor–acceptor structural design

W Ma, LW Luo, P Dong, P Zheng… - Advanced Functional …, 2021 - Wiley Online Library
Recent studies have demonstrated that dihydrophenazine (Pz) with high redox‐reversibility
and high theoretical capacity is an attractive building block to construct p‐type polymer …

Symmetry-breaking charge separation in molecular constructs for efficient light energy conversion

E Sebastian, M Hariharan - ACS Energy Letters, 2022 - ACS Publications
The generation of electron–hole radical pair at the active layer of organic photovoltaics
through symmetry-breaking charge separation (SB-CS) has a crucial role in enhancing open …

[HTML][HTML] Symmetry breaking charge transfer in excited multibranched molecules and dimers: A unified standpoint

AI Ivanov - Journal of Photochemistry and Photobiology C …, 2024 - Elsevier
Symmetry breaking charge transfer (SBCT) in excited molecules plays a central role in
photochemical energy conversion in both artificial and biological systems. The …

High-Efficiency Photoinduced Charge Separation in Fe (III) carbene Thin Films

M Zhang, CE Johnson, A Ilic, J Schwarz… - Journal of the …, 2023 - ACS Publications
Symmetry-breaking charge separation in molecular materials has attracted increasing
attention for optoelectronics based on single-material active layers. To this end, Fe (III) …

Exploring Structure–Property Relations of B, S-Doped Polycyclic Aromatic Hydrocarbons through the Trinity of Synthesis, Spectroscopy, and Theory

T Jin, L Kunze, S Breimaier, M Bolte… - Journal of the …, 2022 - ACS Publications
Polycyclic aromatic hydrocarbons (PAHs) are prominent lead structures for organic
optoelectronic materials. This work describes the synthesis of three B, S-doped PAHs with …

Atomic-scale observation of solvent reorganization influencing photoinduced structural dynamics in a copper complex photosensitizer

T Katayama, TK Choi, D Khakhulin, AO Dohn… - Chemical …, 2023 - pubs.rsc.org
Photochemical reactions in solution are governed by a complex interplay between transient
intramolecular electronic and nuclear structural changes and accompanying solvent …

Symmetry breaking charge transfer leading to charge separation in a far-red absorbing bisstyryl-BODIPY dimer

A Yahagh, RR Kaswan, S Kazemi, PA Karr… - Chemical …, 2024 - pubs.rsc.org
Symmetry breaking charge transfer is one of the important photo-events occurring in
photosynthetic reaction centers that is responsible for initiating electron transfer leading to a …

The Carbene Cannibal: Photoinduced Symmetry-Breaking Charge Separation in an Fe(III) N-Heterocyclic Carbene

N Kaul, R Lomoth - Journal of the American Chemical Society, 2021 - ACS Publications
Photoinduced symmetry-breaking charge separation (SB-CS) processes offer the possibility
of harvesting solar energy by electron transfer between identical molecules. Here, we …

Reducing the internal reorganization energy via symmetry controlled π-electron delocalization

CC Wu, EY Li, PT Chou - Chemical Science, 2022 - pubs.rsc.org
The magnitude of the reorganization energy is closely related to the nonradiative relaxation
rate, which affects the photoemission quantum efficiency, particularly for the emission with a …