Recent advancements in N-ligated group 4 molecular catalysts for the (co) polymerization of ethylene
Abstract Group 4 metal (Zr, Ti, Hf) catalysts for olefin polymerization and specifically those
based on non-metallocene complexes have continued to be a subject of intense study in …
based on non-metallocene complexes have continued to be a subject of intense study in …
Group 4 metal complexes for homogeneous olefin polymerisation: a short tutorial review
RA Collins, AF Russell, P Mountford - Applied Petrochemical Research, 2015 - Springer
The discovery of transition metal-catalysed polymerisation of olefins in the 1950s by Ziegler
and Natta was of huge importance. Over the last 30 years, the interest in homogenous …
and Natta was of huge importance. Over the last 30 years, the interest in homogenous …
Polymerization catalysis with transition metal amidinate and related complexes
S Collins - Coordination Chemistry Reviews, 2011 - Elsevier
Applications of transition metal amidinate [RC (NR′) 2], guanidinate and amidopyridine
complexes to olefin coordination polymerization are reviewed. In addition, the use of …
complexes to olefin coordination polymerization are reviewed. In addition, the use of …
Application of electrophoretic deposition as an advanced technique of inhibited polymer films formation on metals from environmentally safe aqueous solutions of …
NA Shapagina, VV Dushik - Materials, 2022 - mdpi.com
The presented paper analyzes polymer films formed from aqueous solutions of
organosilanes, corrosion inhibitors and their compositions. Methods of depositing inhibited …
organosilanes, corrosion inhibitors and their compositions. Methods of depositing inhibited …
Tailoring Glass Transition Temperature in a Series of Poly(methylene-1,3-cyclopentane-stat-cyclohexane) Statistical Copolymers
WR Burgenson, CM Wentz, LR Sita - ACS Macro Letters, 2023 - ACS Publications
A systematic investigation of the synthesis and characterization of a new class of amorphous
atactic cis, trans poly (methylene-1, 3-cyclopentane-stat-cyclohexane) statistical copolymers …
atactic cis, trans poly (methylene-1, 3-cyclopentane-stat-cyclohexane) statistical copolymers …
Optical Purity as a Programmable Variable for Controlling Polyolefin Tacticity in Living Coordinative Chain Transfer Polymerization: Application to the …
MA Wallace, CM Wentz, LR Sita - ACS Catalysis, 2021 - ACS Publications
Two-state, stereomodulated living coordinative chain transfer polymerization (LCCTP) of 1, 6-
heptadiene has been achieved to produce a series of cis-poly (methylene-1, 3 …
heptadiene has been achieved to produce a series of cis-poly (methylene-1, 3 …
Stereoengineering of poly (1, 3-methylenecyclohexane) via two-state living coordination polymerization of 1, 6-heptadiene
KE Crawford, LR Sita - Journal of the American Chemical Society, 2013 - ACS Publications
External control over the rate of dynamic methyl group exchange between configurationally
stable active species and configurationally unstable dormant species with respect to chain …
stable active species and configurationally unstable dormant species with respect to chain …
Stereo-controlled synthesis of polyolefins with cycloalkane groups by using late transition metals
D Takeuchi - Polymer journal, 2012 - nature.com
Pd complexes with diimine ligands promoted the controlled cyclopolymerization of 1, 6-
dienes and 1, 6, 11-trienes to afford polymers containing 1, 2-trans-cyclopentane groups …
dienes and 1, 6, 11-trienes to afford polymers containing 1, 2-trans-cyclopentane groups …
Ti and Zr complexes of ferrocenyl amidinates
K Multani, LJE Stanlake, DW Stephan - Dalton Transactions, 2010 - pubs.rsc.org
Preparation of a N-ferrocenyl-amidinate complex was achieved by employing (TMEDA) Li
[(CpFeC5H4) NC (Ph) NSiMe3](1) to prepare Cp* Zr [(CpFeC5H4) NC (Ph) NSiMe3] Cl2 (2) …
[(CpFeC5H4) NC (Ph) NSiMe3](1) to prepare Cp* Zr [(CpFeC5H4) NC (Ph) NSiMe3] Cl2 (2) …
Homogeneous Non-Metallocene Group 4 Metals Ligated with [N, N] Bidentate Ligand (s) for Olefin Polymerization
Z Wen, C Wu, J Chen, S Qu, X Li, W Wang - Polymers, 2024 - mdpi.com
The development of catalysts has significantly advanced the progress of polyolefin
materials. In particular, group 4 (Ti, Zr, Hf) non-metallocene catalysts ligated with [N, N] …
materials. In particular, group 4 (Ti, Zr, Hf) non-metallocene catalysts ligated with [N, N] …