Anion effects on spin crossover systems: from supramolecular chemistry to magnetism

SZ Zhao, HW Zhou, CY Qin, HZ Zhang… - … A European Journal, 2023 - Wiley Online Library
The field of anion supramolecular chemistry has received more and more attention in recent
years. Anions with diverse types and geometries have been widely used for the synthesis of …

The First Observation of Hidden Hysteresis in an Iron (III) Spin‐Crossover Complex

T Boonprab, SJ Lee, SG Telfer, KS Murray… - Angewandte …, 2019 - Wiley Online Library
Molecular magnetic switches are expected to form the functional components of future
nanodevices. Herein we combine detailed (photo‐) crystallography and magnetic studies to …

Spin crossover in 3D metal centers binding halide-containing ligands: Magnetism, structure and computational studies

PN Martinho, FF Martins, NAG Bandeira, MJ Calhorda - Sustainability, 2020 - mdpi.com
The capability of a given substance to change its spin state by the action of a stimulus, such
as a change in temperature, is by itself a very challenging property. Its interest is increased …

Solvent Effects on the Structural and Magnetic Properties of FeIII Spin-Crossover Complexes

U Habarakada, T Boonprab, P Harding… - Crystal Growth & …, 2022 - ACS Publications
Molecular devices based on spin-crossover (SCO) compounds are important targets for
molecular electronics. In this study, six air-stable FeIII complexes have been prepared:[Fe …

Effect of Ligand Field Strength on the Spin Crossover Behaviour in 5‐X‐SalEen (X= Me, Br and OMe) Based Fe (III) Complexes

B Dey, A Mondal, S Konar - Chemistry–An Asian Journal, 2020 - Wiley Online Library
The reaction of Fe (NCS) 3 prepared in situ in MeOH with 5‐X‐SalEen ligands (5‐X‐
SalEen= condensation product of 5‐substituted salicylaldehyde and N …

Light and thermally activated spin crossover coupled to an order–disorder transition of a propyl chain in an iron (III) complex

T Boonprab, U Habarakada, G Chastanet, P Harding… - …, 2023 - pubs.rsc.org
A series of three solvates [Fe (naphPren) 2] I· CH2Cl21,[Fe (naphPren) 2] I· CHCl32 and [Fe
(naphPren) 2] I· acetone 3 with the novel ligand HnaphPren {2-([(2-(propylamino) ethyl] …

Halide anion effects and magnetostructural relationships in Iron (III) spin crossover complexes

T Boonprab, W Thammasangwan… - Crystal Growth & …, 2024 - ACS Publications
A series of three compounds [Fe (salEen-5-I) 2] Cl 1,[Fe (salEen-5-I) 2] Br 2, and [Fe (salEen-
5-I) 2] I 3 in which salEen-5-I= 2-{[(2-(ethylamino) ethyl] imino) methyl}-4-iodophenolate is …

Anion-driven supramolecular modulation of spin-crossover properties in mononuclear iron (iii) Schiff-base complexes

ZM Yu, SZ Zhao, YT Wang, PY Xu, CY Qin, YH Li… - Dalton …, 2021 - pubs.rsc.org
A series of Fe (III) complexes [Fe (5-F-sal-N-1, 4, 7, 10)] Y (Y= PF6− for 1, Y= ClO4− for 2, Y=
I− for 3 and Y= NO3− for 4) have been prepared. Single-crystal X-ray crystallographic …

Solvatomorphism, polymorphism and spin crossover in bis [hydrotris (1, 2, 3-triazol-1-yl) borate] iron (II)

OY Horniichuk, K Ridier, G Molnár… - New Journal of …, 2022 - pubs.rsc.org
Solvatomorphism and polymorphism play a crucial role in defining the characteristics of spin
crossover (SCO) in coordination compounds. In this paper we describe a detailed …

Isostructural iron (III) spin crossover complexes with a tridentate Schiff base-like ligand: X-ray structures and magnetic properties

K Dankhoff, B Weber - Dalton Transactions, 2019 - pubs.rsc.org
Here we present two isostructural iron (III) spin crossover complexes with the same
tridentate ligand and perchlorate or tetrafluoroborate as counter ion. Single crystal X-ray …