Defining the macromolecules of tomorrow through synergistic sustainable polymer research

FM Haque, JSA Ishibashi, CAL Lidston, H Shao… - Chemical …, 2022 - ACS Publications
Transforming how plastics are made, unmade, and remade through innovative research and
diverse partnerships that together foster environmental stewardship is critically important to …

Chemical recycling to monomer for an ideal, circular polymer economy

GW Coates, YDYL Getzler - Nature Reviews Materials, 2020 - nature.com
The majority of post-consumer plastic waste is not recycled. Impediments to the recycling of
commodity polymers include separation, impurities and degradation of the macromolecular …

Multifunctional catalysts for ring-opening copolymerizations

CAL Lidston, SM Severson, BA Abel, GW Coates - ACS catalysis, 2022 - ACS Publications
The ring-opening copolymerization (ROCOP) of epoxides with CO2 or cyclic anhydrides is a
versatile route toward synthesizing a wide range of polycarbonate and polyester …

Advances in the use of CO 2 as a renewable feedstock for the synthesis of polymers

B Grignard, S Gennen, C Jérôme, AW Kleij… - Chemical Society …, 2019 - pubs.rsc.org
Carbon dioxide offers an accessible, cheap and renewable carbon feedstock for synthesis.
Current interest in the area of carbon dioxide valorisation aims at new, emerging …

Copolymerization involving sulfur-containing monomers

TJ Yue, WM Ren, XB Lu - Chemical Reviews, 2023 - ACS Publications
Incorporating sulfur (S) atoms into polymer main chains endows these materials with many
attractive features, including a high refractive index, mechanical properties, electrochemical …

Catalysis as an enabling science for sustainable polymers

X Zhang, M Fevre, GO Jones, RM Waymouth - Chemical reviews, 2018 - ACS Publications
The replacement of current petroleum-based plastics with sustainable alternatives is a
crucial but formidable challenge for the modern society. Catalysis presents an enabling tool …

Visible-Light-Driven Catalytic Reductive Carboxylation with CO2

Z Zhang, JH Ye, T Ju, LL Liao, H Huang, YY Gui… - ACS …, 2020 - ACS Publications
Carbon dioxide (CO2) is an important C1 source for the generation of important carboxylic
acids and derivatives. Stoichiometric and catalytic carboxylation of nucleophiles, including …

Polymerization of ethylene oxide, propylene oxide, and other alkylene oxides: synthesis, novel polymer architectures, and bioconjugation

J Herzberger, K Niederer, H Pohlit, J Seiwert… - Chemical …, 2016 - ACS Publications
The review summarizes current trends and developments in the polymerization of alkylene
oxides in the last two decades since 1995, with a particular focus on the most important …

Ring-opening copolymerization of epoxides and cyclic anhydrides with discrete metal complexes: structure–property relationships

JM Longo, MJ Sanford, GW Coates - Chemical reviews, 2016 - ACS Publications
Polyesters synthesized through the alternating copolymerization of epoxides and cyclic
anhydrides compose a growing class of polymers that exhibit an impressive array of …

Stereochemical enhancement of polymer properties

JC Worch, H Prydderch, S Jimaja, P Bexis… - Nature Reviews …, 2019 - nature.com
The importance of stereochemistry to the function of molecules is generally well understood.
However, to date, control over stereochemistry and its potential to influence properties of the …