Photochemical and electrochemical strategies in C–F bond activation and functionalization
Z Wang, Y Sun, LY Shen, WC Yang… - Organic Chemistry …, 2022 - pubs.rsc.org
The activation and functionalization of C–F bonds under mild conditions can serve as an
important tool for organic syntheses including the modification of pharmaceuticals and …
important tool for organic syntheses including the modification of pharmaceuticals and …
Progress in Photoinduced Radical Reactions using Electron Donor‐Acceptor Complexes
L Zheng, L Cai, K Tao, Z Xie, YL Lai… - Asian Journal of …, 2021 - Wiley Online Library
Photocatalyzed organic synthesis transformation is a remarkable green synthetic strategy
because of the advantages of operational simplicity, high chemoselectivities, cheap, and …
because of the advantages of operational simplicity, high chemoselectivities, cheap, and …
Visible‐Light‐Induced Selective Photolysis of Phosphonium Iodide Salts for Monofluoromethylations
Q Liu, Y Lu, H Sheng, CS Zhang, XD Su… - Angewandte Chemie …, 2021 - Wiley Online Library
The sigma (σ)‐hole effect has emerged as a promising tool to construct novel architectures
endowed with new properties. A simple yet effective strategy for the generation of …
endowed with new properties. A simple yet effective strategy for the generation of …
Evolution and Future of Hetero‐and Hydro‐Trifluoromethylations of Unsaturated C− C Bonds
S Kawamura, P Barrio, S Fustero… - Advanced Synthesis …, 2023 - Wiley Online Library
The difunctionalizative trifluoromethylation of unsaturated C− C bonds is a highly useful and
efficient method for the synthesis of trifluoromethyl compounds with attractive architectures …
efficient method for the synthesis of trifluoromethyl compounds with attractive architectures …
Progress in electrochemical trifluoromethylation reactions
RP Bhaskaran, BP Babu - Advanced Synthesis & Catalysis, 2020 - Wiley Online Library
The importance of fluorinated organic molecules in drugs and pharmaceuticals led to the
development of several synthetic methods for introducing fluorine into bioactive molecules …
development of several synthetic methods for introducing fluorine into bioactive molecules …
C–F bond functionalizations of trifluoromethyl groups via radical intermediates
TT Simur, T Ye, YJ Yu, FL Zhang, YF Wang - Chinese Chemical Letters, 2022 - Elsevier
Selective functionalization of C–F bonds in trifluoromethyl groups has recently received a
growing interest, as it offers atom-and step-economic pathways to access highly valuable …
growing interest, as it offers atom-and step-economic pathways to access highly valuable …
Application of Langlois' reagent (NaSO2CF3) in C–H functionalisation
J Shen, J Xu, L He, C Liang, W Li - Chinese Chemical Letters, 2022 - Elsevier
The process of selectively introducing a CF 3 group into an organic molecule using
inexpensive, stable, and solid sodium trifluoromethanesulfinate has rapidly advanced in …
inexpensive, stable, and solid sodium trifluoromethanesulfinate has rapidly advanced in …
Strategies toward the difunctionalizations of enamide derivatives for synthesizing α, β-substituted amines
D Bouchet, T Varlet, G Masson - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Enamide and enecarbamate derivatives containing a nucleophilic center at the
β-position from their nitrogen atom as well as a latent electrophilic site at their α-position are …
β-position from their nitrogen atom as well as a latent electrophilic site at their α-position are …
Pentafluorocyclopropanation of (Hetero) arenes Using Sulfonium Salts: Applications in Late‐Stage Functionalization
Z Feng, L Riemann, Z Guo, D Herrero… - Angewandte …, 2023 - Wiley Online Library
The evaluation of the pentafluorocyclopropyl group as a chemotype in crop protection and
medicinal chemistry has been hampered in the past by the lack of suitable methodologies …
medicinal chemistry has been hampered in the past by the lack of suitable methodologies …
Designing radical chemistry by visible light-promoted homolysis
The use of visible light to promote synthetic processes has been emerging rapidly in recent
years. In the frame of eco-sustainable strategies involving the generation of reactive …
years. In the frame of eco-sustainable strategies involving the generation of reactive …