Characterization of naphthenic acids in crude oil samples–A literature review

EV Barros, PR Filgueiras, V Lacerda Jr, RP Rodgers… - Fuel, 2022 - Elsevier
Given the ill-defined term “naphthenic acids”(NAs), we will classify NAs as the carboxylic
acids found naturally in crude oil, which include both classic NAs (c-NAs, monoacids) and ox …

High-efficiency separation and extraction of naphthenic acid from high acid oils using imidazolium carbonate ionic liquids

F Geng, R Zhang, L Wu, Z Tang, H Liu, H Liu… - Chinese Journal of …, 2022 - Elsevier
N-alkyl imidazolium carbonate ionic liquids were employed to separate and recover
naphthenic acid from model oils. The effects of the cationic and anionic structures of ionic …

Molecular interactions between 1-butyl-3-methylimidazolium tetrafluoroborate and model naphthenic acids: a DFT study

C Wu, A De Visscher, ID Gates - Journal of Molecular Liquids, 2017 - Elsevier
A density functional theory study was performed to investigate the interactions between 1-
butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF 4]) and six different model …

Oil acidity reduction by extraction with imidazolium ionic liquids: Experimental, COSMO description and reutilization study

B Coto, I Suarez, MJ Tenorio, S Nieto, N Alvarez… - Separation and …, 2021 - Elsevier
Crude oil acidity, usually quantified through total acid number (TAN) and mainly due to
carboxylic compounds, is a main problem because causes high corrosion rates and fouling …

Thermodynamic modelling of liquid-liquid extraction systems involving ionic liquids: a new approach

H Suleman, AS Maulud, SN Shah, Z Man… - Journal of Molecular …, 2018 - Elsevier
In this study, a new approach is introduced for the thermodynamic correlation of liquid-liquid
extraction (LLE) systems involving ionic liquids (ILs). The model incorporates the effect of …

Extraction of toluene and n-heptane mixture using ionic liquid Aliquat 336 and mathematical modeling for solvent selection

SP Kodolikar Kulkarni, DS Bhatkhande… - Separation Science …, 2018 - Taylor & Francis
Liquid–liquid equilibrium data for the system consisting of toluene, n-heptane and Aliquat
336 ionic liquid was obtained at 303.15 K and atmospheric pressure. The values of …

[PDF][PDF] Recent techniques for the removal of naphthenic acid from heavy crude oils

FV Adams, CE Chukwuneke… - Processing of Heavy …, 2019 - library.oapen.org
Naphthenic acid (NA) is one of the components of heavy crude oil. It is composed of a
carboxylic acid functional group attached to a hydrocarbon molecule. Heavy crude oils with …

Adamantane-Based Cation and [MFn] Anion Synergistically Enhanced Catalytic Performance of Sulfuric Acid for Isobutane Alkylation

L Wang, G Zhao, X Yao, B Ren… - Industrial & Engineering …, 2017 - ACS Publications
A series of adamantane-based ionic liquids (ADM-ILs) with [MF n]− anions were synthesized
as cocatalysts for the alkylation of isobutane and butene. By systematically tuning the …

Predicting naphthenate precipitation and evaluating the effect of ionic liquids on its deposition

AA Sulaimon, AN Masri, UAAJ Sabri… - Journal of Petroleum …, 2022 - Elsevier
Naphthenic acids that are naturally carboxylic compounds contained in heavy crude oil are
the main source of corrosion and blockage in a crude oil pipeline. The blockage is due to the …

[HTML][HTML] A Techno-Economic Study of Catalytic Decarboxylation Process for Naphthenic Acids Utilizing Protonic Zeolite Socony Mobil Type 5 (HZSM-5) Catalyst

NO Hassan, G Ibrahim, DM Beshir, NO Elbashir - Processes, 2023 - mdpi.com
This paper represents a detailed techno-economic analysis of a typical commercial-scale
catalytic decarboxylation process of naphthenic acids over HZSM-5 zeolite. Simulation of the …